The Interhalogen Cations [Br2F5]+ and [Br3F8]+
| dc.contributor | Aalto-yliopisto | fi |
| dc.contributor | Aalto University | en |
| dc.contributor.author | Ivlev, Sergei I. | en_US |
| dc.contributor.author | Karttunen, Antti J. | en_US |
| dc.contributor.author | Buchner, Magnus R. | en_US |
| dc.contributor.author | Conrad, Matthias | en_US |
| dc.contributor.author | Kraus, Florian | en_US |
| dc.contributor.department | Department of Chemistry and Materials Science | en |
| dc.contributor.groupauthor | Inorganic Materials Modelling | en |
| dc.contributor.organization | University of Marburg | en_US |
| dc.date.accessioned | 2018-11-02T08:45:33Z | |
| dc.date.available | 2018-11-02T08:45:33Z | |
| dc.date.embargo | info:eu-repo/date/embargoEnd/2019-10-27 | en_US |
| dc.date.issued | 2018-10-26 | en_US |
| dc.description | HUOM! TÄMÄ MANUSKA oli TILASSA CLOSED KUNNES ARTIKKELI JULKAISTiin JA JULKAISUVIIVE MÄÄRITELTiin KUSTANTAJAN JULKAISUPÄIVÄSTÄ ALKAEN. The manuscript was ""closed"" until the article was published and the embargo date could be defined. | |
| dc.description.abstract | The synthesis and characterization of unique polyhalogen cations containing μ-bridging fluorine atoms are reported. The [Br2F5]+ cation features a symmetric [F2Br-μ-F-BrF2] bridge, whereas the [Br3F8]+ contains asymmetric μ-F bridges. These fluoronium ions, obtained as [SbF6]- salts, were investigated using Raman and 19FNMR spectroscopy, as well as single-crystal X-ray diffraction. Quantum chemical calculations were carried out for the gas-phase cations as well as for the solid-state compounds. Population analyses show the μ-F atoms to possess the most negative partial charge within the cations. | en |
| dc.description.version | Peer reviewed | en |
| dc.format.mimetype | application/pdf | en_US |
| dc.identifier.citation | Ivlev, S I, Karttunen, A J, Buchner, M R, Conrad, M & Kraus, F 2018, ' The Interhalogen Cations [Br 2 F 5 ] + and [Br 3 F 8 ] + ', Angewandte Chemie - International Edition, vol. 57, pp. 14640–14644 . https://doi.org/10.1002/anie.201803708 | en |
| dc.identifier.doi | 10.1002/anie.201803708 | en_US |
| dc.identifier.issn | 1433-7851 | |
| dc.identifier.other | PURE UUID: fa9e7308-946c-43f0-b2f2-90f1a4d5e070 | en_US |
| dc.identifier.other | PURE ITEMURL: https://research.aalto.fi/en/publications/fa9e7308-946c-43f0-b2f2-90f1a4d5e070 | en_US |
| dc.identifier.other | PURE LINK: http://www.scopus.com/inward/record.url?scp=85047734589&partnerID=8YFLogxK | |
| dc.identifier.other | PURE FILEURL: https://research.aalto.fi/files/25728874/CHEM_Ivlev_et_al_Interhalogen_Cations_2018_Angewandte_Chemie.pdf | en_US |
| dc.identifier.uri | https://aaltodoc.aalto.fi/handle/123456789/34549 | |
| dc.identifier.urn | URN:NBN:fi:aalto-201811025602 | |
| dc.language.iso | en | en |
| dc.publisher | Wiley | |
| dc.relation.ispartofseries | Angewandte Chemie - International Edition | en |
| dc.relation.ispartofseries | Volume 57, pp. 14640–14644 | en |
| dc.rights | openAccess | en |
| dc.subject.keyword | Antimony pentafluoride | en_US |
| dc.subject.keyword | Bromine trifluoride | en_US |
| dc.subject.keyword | Fluoronium ions | en_US |
| dc.subject.keyword | Heteropolyhalogen cations | en_US |
| dc.subject.keyword | Structure elucidation | en_US |
| dc.title | The Interhalogen Cations [Br2F5]+ and [Br3F8]+ | en |
| dc.type | A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä | fi |
| dc.type.version | acceptedVersion |