Fertiliser Properties of Wastewater Sludge and Sludge Ash - A Case Study from the Finnish Forest Industry

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Volume Title

A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

Date

2023-03-01

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Mcode

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Language

en

Pages

16
63-78

Series

Ecological Chemistry and Engineering S, Volume 30, issue 1

Abstract

In this case study we compared the fertiliser properties of an industrial wastewater treatment sludge and a sludge ash to the requirements of the Finnish Fertiliser Product Decree. The sludge was obtained from the activated sludge wastewater treatment plant of a Finnish non-integrated pulp mill. The sludge was furthermore incinerated at a laboratory in a muffle furnace (850 °C) to obtain sludge ash. The total Cd (4.9 mg/kg d.m.) concentration in the pulp sludge exceeded the Finnish limit value (1.5 mg/kg d.m.) for fertiliser products used in agriculture. In the sludge ash, the total concentration of Cd (39 mg/kg; d.m.) exceeded the Finnish limit value (25 mg/kg d.m.) for ash fertilisers used in forestry. These results restrict the potential reuse options of these residues. However, from the utilisation point of view, the enrichment of essential plant macro-nutrients was most notable, resulting to the following total concentrations of these elements in the sludge ash: P (26,000 mg/kg d.m.), S (40,000 mg/kg d.m.), K (11,000 mg/kg d.m.), Ca (83,000 mg/kg d.m.) and Mg (10,000 mg/kg d.m.). Therefore, we conclude that, the converting of sludge into ash may promote the reuse of this wastewater treatment residue to a more value-adding fertiliser by-product to be used as a soil improver and growing medium in landscaping or landfills sites or other closed industrial areas, where heavy metal limit values for fertilisers are not applied in Finland.

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Publisher Copyright: © 2023 Juha Oksanen et al., published by Sciendo.

Keywords

ash, circular economy, extraction, fertiliser, pulp mill, sludge, waste, wastewater treatment

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Citation

Oksanen, J, Pöykiö, R & Dahl, O 2023, ' Fertiliser Properties of Wastewater Sludge and Sludge Ash - A Case Study from the Finnish Forest Industry ', Ecological Chemistry and Engineering S, vol. 30, no. 1, pp. 63-78 . https://doi.org/10.2478/eces-2023-0004