Development of thin metal anodes by vacuum deposition technology from raw and recycled lithium for solid-state battery and anolyte interlayer

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Journal Title

Journal ISSN

Volume Title

Kemian tekniikan korkeakoulu | Master's thesis

Date

2022-10-18

Department

Major/Subject

Functional Materials for Global Challenges

Mcode

CHEM3061

Degree programme

Master's Programme in Advanced Materials for Innovation and Sustainability

Language

en

Pages

56 + 8

Series

Abstract

In a context of ecological concerns, the evolution of batteries is at the centre of the energy transition. From 2035 onwards, the sale of thermal cars will no longer be permitted in the European Union. Lithium metal, considered the holy grail of anode materials due to its extremely high specific capacity and low negative redox potential, is currently one of the best solutions for improving battery performance. Apart from safety issues that limit its use, supply complications are expected in the future. The proper management of lithium resources in the European Union is a priority; the need for lithium must be reduced and its recyclability increased. In order to address this problem, this master thesis investigates a thin film vapour deposition process that reduces the amount of lithium used in batteries and allows the use of lithium from the recycling industry. The paper describes the implementation of a vacuum evaporation process as well as the methods used to characterize the thin films of lithium. As the purity of lithium is an important factor for the durability and safety of the battery, it is shown that the evaporation process allows purification and therefore the use of recycled lithium with impurities.

Description

Supervisor

Murtomäki, Lasse

Thesis advisor

Lafort, Adeline
Fourdrinier, Lionel

Keywords

lithium metal anode, physical vapor deposition, all-solid-state battery, energetic transition, lithium recycling

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