Stable glycosylamines at the reducing ends of cellulose nanocrystals
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A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä
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Date
2023-08-07
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en
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4
9408-9411
9408-9411
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Chemical Communications, Volume 59, issue 61
Abstract
The reaction of reducing end groups in cellulose nanocrystals with dodecylamine was examined. Using a direct-dissolution solution-state NMR protocol, the regioselective formation of glucosylamines was shown. This provides an elegant approach to sustainably functionalize these bio-based nanomaterials, that may not require further reduction to more stable secondary amines.Description
The authors wish to acknowledge the Research Council of Finland for funding (Project's: 310481 & 311255). The facilities and expertise of the HiLIFE NMR unit at the University of Helsinki, a member of Instruct-ERIC Centre Finland, FINStruct, and Biocenter Finland are gratefully acknowledged.
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Xia, J, Koso, T, Heise, K, Fliri, L, Ressouche, E, Majoinen, J, Kostiainen, M A, Hietala, S, Hummel, M, Aseyev, V, Kilpeläinen, I & King, A W T 2023, ' Stable glycosylamines at the reducing ends of cellulose nanocrystals ', Chemical Communications, vol. 59, no. 61, pp. 9408-9411 . https://doi.org/10.1039/d3cc01329d