Platelet CuSbS2 particles with a suitable conduction band position for solar cell applications

No Thumbnail Available

Access rights

openAccess
acceptedVersion

URL

Journal Title

Journal ISSN

Volume Title

A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

Date

2018-03-15

Major/Subject

Mcode

Degree programme

Language

en

Pages

4

Series

Materials Letters, Volume 215, pp. 157-160

Abstract

Single crystalline platelet chalcostibite (CuSbS2) particles with good shape and size uniformity were successfully prepared using a hot injection method. In this synthesis, sulfur powder in oleylamine (OLA) was employed as a sulfonating agent. The synthesized CuSbS2 had an orthorhombic structure with a plate-like morphology. Selected area electron diffraction (SAED) patterns confirmed their single crystal nature. Band gap calculation from diffuse reflectance data revealed that it had both direct and indirect band gaps of 1.52 eV and 1.46 eV, respectively. Moreover, valence band (VB) and conduction band (CB) positions were determined by cyclic voltammetry (CV) characterization. Optical and structural properties of CuSbS2 indicate its potential applicability for solar cell applications. (C) 2017 Elsevier B.V. All rights reserved.

Description

Keywords

Copper antimony sulfide, Crystal structure, Band gap, Valence band, Conduction band, COPPER ANTIMONY SULFIDE, ABSORBER MATERIALS, SE

Other note

Citation

Moosakhani, S, Alvani, A A S, Mohammadpour, R, Hannula, P-M, Ge, Y & Hannula, S-P 2018, ' Platelet CuSbS2 particles with a suitable conduction band position for solar cell applications ', Materials Letters, vol. 215, pp. 157-160 . https://doi.org/10.1016/j.matlet.2017.12.084