Biopolymer Filtration in Corrugated Nanochannels

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© 2014 American Physical Society (APS). http://www.aps.org/
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Journal Title

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Volume Title

School of Science | A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

Date

2014

Major/Subject

Mcode

Degree programme

Language

en

Pages

118301/1-5

Series

Physical Review Letters, Volume 112, Issue 11

Abstract

We examine pressure-driven nonequilibrium transport of linear, circular, and star polymers through a nanochannel containing a rectangular pit with full hydrodynamic interactions and thermal fluctuations. We demonstrate that with sufficiently small pressure differences, there is contour length-dependent entropic trapping of the polymer in the pit when the pit and the polymer sizes are compatible. This is due to competition between flow and chain relaxation in the pit, which leads to a nonmonotonic dependence of the polymer mobility on its size and should aid in the design of nanofiltration devices based on the polymer size and shape.

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Keywords

lattice boltzmann, polymers, filtration, nanochannels, thermal fluctuations

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Citation

Ollila, Santtu T. T. & Denniston, Colin & Karttunen, Mikko & Ala-Nissilä, Tapio. 2014. Biopolymer Filtration in Corrugated Nanochannels. Physical Review Letters. Volume 112, Issue 11. P. 118301/1-5. ISSN 0031-9007 (printed). DOI: 10.1103/physrevlett.112.118301.