Tuning the Porosity, Water Interaction, and Redispersion of Nanocellulose Hydrogels by Osmotic Dehydration

dc.contributorAalto-yliopistofi
dc.contributorAalto Universityen
dc.contributor.authorGuccini, Valentinaen_US
dc.contributor.authorPhiri, Josphaten_US
dc.contributor.authorTrifol, Jonen_US
dc.contributor.authorRissanen, Villeen_US
dc.contributor.authorMousavi, Seyede Maryamen_US
dc.contributor.authorVapaavuori, Jaanaen_US
dc.contributor.authorTammelin, Teklaen_US
dc.contributor.authorMaloney, Thaddeusen_US
dc.contributor.authorKontturi, Eeroen_US
dc.contributor.departmentDepartment of Bioproducts and Biosystemsen
dc.contributor.departmentDepartment of Chemical and Metallurgical Engineeringen
dc.contributor.departmentDepartment of Chemistry and Materials Scienceen
dc.contributor.groupauthorMaterials Chemistry of Celluloseen
dc.contributor.groupauthorBio-based Materialsen
dc.contributor.groupauthorPolymer technologyen
dc.contributor.groupauthorMultifunctional Materials Designen
dc.contributor.organizationVTT Technical Research Centre of Finlanden_US
dc.date.accessioned2022-01-10T08:15:27Z
dc.date.available2022-01-10T08:15:27Z
dc.date.issued2022-01-14en_US
dc.description| openaire: EC/H2020/899576/EU//FuturoLEAF | openaire: EC/H2020/949648/EU//ModelCom V.G. and E.K. would like to acknowledge the Academy of Finland (AoF) for the Financial support by the Project AlgaLEAF (Project 322755). V.R. and T.T. would like to acknowledge the European Union via the project FuturoLEAF (European Union’s Horizon 2020 research and innovation programme under grant agreement no. 899576). J.P. and T.M. would like to acknowledge the Foundation for Research of Natural Resources in Finland. M.M. and J.V. would like to acknowledge the European Commission for generous funding for the ModelCom project. J.T. would like to acknowledge the AoF’s Flagship Programme, Projects . 318890 and 318891 (Competence Center for Materials Bioeconomy, FinnCERES). This work utilized facilities provided by the RawMatters Finland Infrastructure (RAMI) at Aalto University, supported by AoF, and the facilities and technical support of the OtaNano Nanomicroscopy Center (Aalto-NMC).
dc.description.abstractOsmotic dehydration (OD) was introduced as a method to reproducibly tune the water content and porosity of cellulose nanofiber (CNF) hydrogels. The hierarchical porosity was followed by electron microscopy (pores with a >100 μm diameter) and thermoporosimetry (mesopores), together with mechanical testing, in hydrogels with solid contents ranging from 0.7 to 12 wt %. Furthermore, a reciprocal correlation between proton conductivity and the ratio of water bound to the nanocellulose network was established, suggesting the potential of these systems toward tunable energy materials.en
dc.description.versionPeer revieweden
dc.format.extent5
dc.format.mimetypeapplication/pdfen_US
dc.identifier.citationGuccini, V, Phiri, J, Trifol, J, Rissanen, V, Mousavi, S M, Vapaavuori, J, Tammelin, T, Maloney, T & Kontturi, E 2022, 'Tuning the Porosity, Water Interaction, and Redispersion of Nanocellulose Hydrogels by Osmotic Dehydration', ACS Applied Polymer Materials, vol. 4, no. 1, pp. 24-28. https://doi.org/10.1021/acsapm.1c01430en
dc.identifier.doi10.1021/acsapm.1c01430en_US
dc.identifier.issn2637-6105
dc.identifier.otherPURE UUID: 26642c1a-3da7-4bf8-80b9-efaeb24d9eaeen_US
dc.identifier.otherPURE ITEMURL: https://research.aalto.fi/en/publications/26642c1a-3da7-4bf8-80b9-efaeb24d9eaeen_US
dc.identifier.otherPURE FILEURL: https://research.aalto.fi/files/80229512/CHEM_Guccini_et_al_Tuning_the_Porosity_2022_ACS_Applied_Polymer_Materials.pdf
dc.identifier.urihttps://aaltodoc.aalto.fi/handle/123456789/112144
dc.identifier.urnURN:NBN:fi:aalto-202201101056
dc.language.isoenen
dc.publisherAmerican Chemical Society
dc.relationinfo:eu-repo/grantAgreement/EC/H2020/949648/EU//ModelCom V.G. and E.K. would like to acknowledge the Academy of Finland (AoF) for the Financial support by the Project AlgaLEAF (Project 322755). V.R. and T.T. would like to acknowledge the European Union via the project FuturoLEAF (European Union’s Horizon 2020 research and innovation programme under grant agreement no. 899576). J.P. and T.M. would like to acknowledge the Foundation for Research of Natural Resources in Finland. M.M. and J.V. would like to acknowledge the European Commission for generous funding for the ModelCom project. J.T. would like to acknowledge the AoF’s Flagship Programme, Projects . 318890 and 318891 (Competence Center for Materials Bioeconomy, FinnCERES). This work utilized facilities provided by the RawMatters Finland Infrastructure (RAMI) at Aalto University, supported by AoF, and the facilities and technical support of the OtaNano Nanomicroscopy Center (Aalto-NMC).en_US
dc.relation.ispartofseriesACS Applied Polymer Materialsen
dc.relation.ispartofseriesVolume 4, issue 1, pp. 24-28en
dc.rightsopenAccessen
dc.titleTuning the Porosity, Water Interaction, and Redispersion of Nanocellulose Hydrogels by Osmotic Dehydrationen
dc.typeLetterfi
dc.type.versionpublishedVersion

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