Strong Second Harmonic Generation from Bilayer Graphene with Symmetry Breaking by Redox-Governed Charge Doping

dc.contributorAalto-yliopistofi
dc.contributorAalto Universityen
dc.contributor.authorZhang, Mingwenen_US
dc.contributor.authorHan, Nannanen_US
dc.contributor.authorWang, Jingen_US
dc.contributor.authorZhang, Zhihongen_US
dc.contributor.authorLiu, Kaihuien_US
dc.contributor.authorSun, Zhipeien_US
dc.contributor.authorZhao, Jianlinen_US
dc.contributor.authorGan, Xuetaoen_US
dc.contributor.departmentNorthwestern Polytechnical Universityen_US
dc.contributor.departmentPeking Universityen_US
dc.contributor.departmentDepartment of Electronics and Nanoengineeringen_US
dc.date.accessioned2022-06-22T09:01:25Z
dc.date.available2022-06-22T09:01:25Z
dc.date.embargoinfo:eu-repo/date/embargoEnd/2023-05-24en_US
dc.date.issued2022-05-24en_US
dc.descriptionFunding Information: This work is supported by the National Key R&D Program of China (Grants 2018YFA0307200 and 2017YFA0303800), the National Natural Science Foundation of China (Grants 61775183, 11634010, and 61905196), the Key R&D Program of Shaanxi Province (Grant 2020JZ-10), Key R&D Program of Guangdong Province (Grants 2020B010189001, 2019B010931001, and 2018B030327001), and the Fundamental Research Funds for the Central Universities (Grants 3102017jc01001, 3102019JC008, and 310201911cx032). Publisher Copyright: © 2022 American Chemical Society.
dc.description.abstractMissing second-order nonlinearity in centrosymmetric graphene overshadows its intriguing optical attribute. Here, we report redox-governed charge doping could effectively break the centrosymmetry of bilayer graphene (BLG), enabling a strong second harmonic generation (SHG) with a strength close to that of the well-known monolayer MoS2. Verified from control experiments with in situ electrical current annealing and electrically gate-controlled SHG, the required centrosymmetry breaking of the emerging SHG arises from the charge-doping on the bottom layer of BLG by the oxygen/water redox couple. Our results not only reveal that charge doping is an effective way to break the inversion symmetry of BLG despite its strong interlayer coupling but also indicate that SHG spectroscopy is a valid technique to probe molecular doping on two-dimensional materials.en
dc.description.versionPeer revieweden
dc.format.extent7
dc.format.extent4287-4293
dc.format.mimetypeapplication/pdfen_US
dc.identifier.citationZhang , M , Han , N , Wang , J , Zhang , Z , Liu , K , Sun , Z , Zhao , J & Gan , X 2022 , ' Strong Second Harmonic Generation from Bilayer Graphene with Symmetry Breaking by Redox-Governed Charge Doping ' , Nano Letters , vol. 22 , no. 11 , pp. 4287-4293 . https://doi.org/10.1021/acs.nanolett.1c04359en
dc.identifier.doi10.1021/acs.nanolett.1c04359en_US
dc.identifier.issn1530-6984
dc.identifier.issn1530-6992
dc.identifier.otherPURE UUID: 29388327-21f3-4104-82a2-c84d8a87f246en_US
dc.identifier.otherPURE ITEMURL: https://research.aalto.fi/en/publications/29388327-21f3-4104-82a2-c84d8a87f246en_US
dc.identifier.otherPURE LINK: http://www.scopus.com/inward/record.url?scp=85131661492&partnerID=8YFLogxKen_US
dc.identifier.otherPURE FILEURL: https://research.aalto.fi/files/84747001/SHG_BLG.pdfen_US
dc.identifier.urihttps://aaltodoc.aalto.fi/handle/123456789/115309
dc.identifier.urnURN:NBN:fi:aalto-202206224149
dc.language.isoenen
dc.publisherAMERICAN CHEMICAL SOCIETY
dc.relation.ispartofseriesNano Lettersen
dc.relation.ispartofseriesVolume 22, issue 11en
dc.rightsopenAccessen
dc.subject.keywordbilayer grapheneen_US
dc.subject.keywordcharge transferen_US
dc.subject.keywordoxygen reduction reactionen_US
dc.subject.keywordsecond harmonic generationen_US
dc.subject.keywordsymmetry breakingen_US
dc.titleStrong Second Harmonic Generation from Bilayer Graphene with Symmetry Breaking by Redox-Governed Charge Dopingen
dc.typeA1 Alkuperäisartikkeli tieteellisessä aikakauslehdessäfi
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