Effect of potential energy distribution on the melting of clusters

Loading...
Thumbnail Image

Access rights

openAccess
publishedVersion

URL

Journal Title

Journal ISSN

Volume Title

A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

Date

Major/Subject

Mcode

Degree programme

Language

en

Pages

Series

Physical Review Letters, Volume 86, issue 6, pp. 999-1002

Abstract

We find that the potential energy distribution of atoms in clusters can consistently explain many important phenomena related to the phase changes of clusters, such as the nonmonotonic variation of melting temperature with size, the dependence of melting, boiling, and sublimation temperatures on the interatomic potentials, the existence of a surface-melted phase, and the absence of a premelting peak in heat capacity curves. We also find a new type of premelting mechanism in double icosahedral Pd19 clusters, where one of the two internal atoms escapes to the surface at the premelting temperature.

Description

Keywords

Other note

Citation

Lee, Y-J, Lee, E -K & Nieminen, R M 2001, 'Effect of potential energy distribution on the melting of clusters', Physical Review Letters, vol. 86, no. 6, pp. 999-1002. https://doi.org/10.1103/PhysRevLett.86.999