Application-Specific Catalyst Layers

dc.contributorAalto-yliopistofi
dc.contributorAalto Universityen
dc.contributor.authorLaurila, Tomi
dc.contributor.authorSainio, Sami
dc.contributor.authorJiang, Hua
dc.contributor.authorIsoaho, Noora
dc.contributor.authorKoehne, Jessica
dc.contributor.authorEtula, Jarkko
dc.contributor.authorKoskinen, Jari
dc.contributor.authorMeyyappan, M.
dc.contributor.departmentDepartment of Electrical Engineering and Automation
dc.contributor.departmentDepartment of Applied Physics
dc.contributor.departmentNASA Ames Research Center
dc.contributor.departmentDepartment of Chemistry and Materials Science
dc.date.accessioned2017-03-23T12:48:24Z
dc.date.available2017-03-23T12:48:24Z
dc.date.issued2017-02-13
dc.description.abstractComplete removal of metal catalyst particles from carbon nanofibers (CNFs) and other carbon nanostructures is extremely difficult, and the envisioned applications may be compromised by the left-over impurities. To circumvent these problems, one should use, wherever possible, such catalyst materials that are meant to remain in the structure and have some application-specific role, making any removal steps unnecessary. Thus, as a proof-of-concept, we present here a nanocarbon-based material platform for electrochemical hydrogen peroxide measurement utilizing a Pt catalyst layer to grow CNFs with intact Pt particles at the tips of the CNFs. Backed by careful scanning transmission electron microscopy analysis, we show that this material can be readily realized with the Pt catalyst layer thickness impacting the resulting structure and also present a growth model to explain the evolution of the different types of structures. In addition, we show by electrochemical analysis that the material exhibits characteristic features of Pt in cyclic voltammetry and it can detect very small amounts of hydrogen peroxide with very fast response times. Thus, the present sensor platform provides an interesting electrode material with potential for biomolecule detection and in fuel cells and batteries. In the wider range, we propose a new approach where the selection of catalytic particles used for carbon nanostructure growth is made so that (i) they do not need to be removed and (ii) they will have essential role in the final application.en
dc.description.versionPeer revieweden
dc.format.extent496-507
dc.format.mimetypeapplication/pdf
dc.identifier.citationLaurila , T , Sainio , S , Jiang , H , Isoaho , N , Koehne , J , Etula , J , Koskinen , J & Meyyappan , M 2017 , ' Application-Specific Catalyst Layers : Pt-Containing Carbon Nanofibers for Hydrogen Peroxide Detection ' , ACS Omega , vol. 2 , no. 2 , pp. 496-507 . https://doi.org/10.1021/acsomega.6b00441en
dc.identifier.doi10.1021/acsomega.6b00441
dc.identifier.issn2470-1343
dc.identifier.otherPURE UUID: c11fbb51-4ddb-4f94-b670-41e618b11010
dc.identifier.otherPURE ITEMURL: https://research.aalto.fi/en/publications/c11fbb51-4ddb-4f94-b670-41e618b11010
dc.identifier.otherPURE FILEURL: https://research.aalto.fi/files/11520101/acsomega.6b00441.pdf
dc.identifier.urihttps://aaltodoc.aalto.fi/handle/123456789/24938
dc.identifier.urnURN:NBN:fi:aalto-201703233181
dc.language.isoenen
dc.relation.ispartofseriesACS Omegaen
dc.relation.ispartofseriesVolume 2en
dc.rightsopenAccessen
dc.titleApplication-Specific Catalyst Layersen
dc.typeA1 Alkuperäisartikkeli tieteellisessä aikakauslehdessäfi
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