A Comprehensive Study on the Full Series of Alkali-Metal Selenocyanates AI[SeCN] (AI=Li−Cs)

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dc.contributorAalto-yliopistofi
dc.contributorAalto Universityen
dc.contributor.authorShlyaykher, Alenaen_US
dc.contributor.authorEhmann, Marvinen_US
dc.contributor.authorKarttunen, Antti J.en_US
dc.contributor.authorTambornino, Franken_US
dc.contributor.departmentDepartment of Chemistry and Materials Scienceen
dc.contributor.groupauthorInorganic Materials Modellingen
dc.contributor.organizationUniversity of Marburgen_US
dc.date.accessioned2021-10-06T06:41:59Z
dc.date.available2021-10-06T06:41:59Z
dc.date.issued2021-09-24en_US
dc.descriptionFunding Information: F.T. thanks the Fonds der Chemischen Industrie for a Liebig fellowship. F.T. thanks Prof. Dehnen for excellent support, Prof. Müller and Prof. Kraus for discussions on the crystal structures. Dr. Radostan Riedel is gratefully acknowledged for measuring the single crystal dataset of Na[SeCN]. Jonathan Pfeiffer is gratefully acknowledged for measuring the Raman data. Open access funding enabled and organized by Projekt DEAL. Publisher Copyright: © 2021 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH
dc.description.abstractThe full series of quasibinary alkali-metal selenocyanates was synthesized either by oxidation of the respective cyanides (A=Li−Rb) or by metathesis (A=Cs). For Li[SeCN] only ball-milling and subsequent annealing led to the isolation of the quasibinary selenocyanate. Their structures were refined from single-crystal and powder X-ray data. The respective solid-state IR and Raman spectra were interpreted with the aid of solid-state quantum-mechanical calculations and DSC-TGA measurements allowed for extraction of melting points. Only for Li[SeCN] a possible phase transition was observed that is discussed on the basis of VT-PXRD experiments. It is also the only quasibinary selenocyanate to form a hydrate (Li[SeCN] ⋅ 2H2O).en
dc.description.versionPeer revieweden
dc.format.extent6
dc.format.mimetypeapplication/pdfen_US
dc.identifier.citationShlyaykher, A, Ehmann, M, Karttunen, A J & Tambornino, F 2021, 'A Comprehensive Study on the Full Series of Alkali-Metal Selenocyanates A I [SeCN] (A I =Li−Cs)', Chemistry: A European Journal, vol. 27, no. 54, pp. 13552-13557. https://doi.org/10.1002/chem.202102058en
dc.identifier.doi10.1002/chem.202102058en_US
dc.identifier.issn0947-6539
dc.identifier.issn1521-3765
dc.identifier.otherPURE UUID: aa425e2b-b7ca-4bc3-a66d-abcbed64de24en_US
dc.identifier.otherPURE ITEMURL: https://research.aalto.fi/en/publications/aa425e2b-b7ca-4bc3-a66d-abcbed64de24en_US
dc.identifier.otherPURE LINK: http://www.scopus.com/inward/record.url?scp=85112775162&partnerID=8YFLogxK
dc.identifier.otherPURE FILEURL: https://research.aalto.fi/files/67996636/CHEM_Shlyaykher_et_al_A_Comprehensive_Study_2021_Chemistry_A_European_Journal.pdfen_US
dc.identifier.urihttps://aaltodoc.aalto.fi/handle/123456789/110334
dc.identifier.urnURN:NBN:fi:aalto-202110069529
dc.language.isoenen
dc.publisherWiley
dc.relation.ispartofseriesChemistry: A European Journalen
dc.relation.ispartofseriesVolume 27, issue 54, pp. 13552-13557en
dc.rightsopenAccessen
dc.subject.keywordalkali-metalsen_US
dc.subject.keywordcrystallographyen_US
dc.subject.keywordselenocyanatesen_US
dc.subject.keywordsolid-phase synthesisen_US
dc.subject.keywordvibrational spectroscopyen_US
dc.titleA Comprehensive Study on the Full Series of Alkali-Metal Selenocyanates AI[SeCN] (AI=Li−Cs)en
dc.typeA1 Alkuperäisartikkeli tieteellisessä aikakauslehdessäfi
dc.type.versionpublishedVersion

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