Self-assembly of colloidal lignin particles in a continuous flow tubular reactor

No Thumbnail Available
Access rights
openAccess
Journal Title
Journal ISSN
Volume Title
A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä
This publication is imported from Aalto University research portal.
View publication in the Research portal
View/Open full text file from the Research portal
Date
2020-02-20
Major/Subject
Mcode
Degree programme
Language
en
Pages
Series
Colloids and Surfaces A: Physicochemical and Engineering Aspects, Volume 587
Abstract
A scalable tubular flow reactor was designed and developed for the continuous formation of colloidal lignin particles (CLPs). The reactor consists of a series of tubes, inside which many static mixing elements are equipped to aid in the formation of a homogeneous dispersion of CLPs. The colloids were formed instantaneously through self-assembly upon the addition of the lignin solution into water. The effects of flowrate, length of the tubes and static mixing elements on the particle size, stability and CLP yield after drying were determined. It was found that a higher flowrate of lignin solution within the testing range of 32-240 mL/min resulted in smaller sized CLPs. Optimizations of the mixing length and the static mixing elements to 3 m and at least 1 m, respectively, could ensure an efficient mixing, thus resulting in CLP dispersions with smaller size of lignin particles (200 nm – 400 nm) and high lignin concentrations (up to 2.8 wt. %) along with yields up to 95 %. The TEM images indicated that the formed colloids are composed of lignin particles of regular sphere shape and with good stability. The tubular reactor offers better control of particle size which ensures the formation of colloidal dispersions with narrower particle size distribution in comparison to a stirred mixer reactor. Furthermore, using a tubular reactor enables the continuous production of CLPs, making it suitable for scale up and industrial applications.
Description
Keywords
Other note
Citation
Bangalore Ashok , R , Xiao , Y , Lintinen , K , Oinas , P , Kostiainen , M & Österberg , M 2020 , ' Self-assembly of colloidal lignin particles in a continuous flow tubular reactor ' , Colloids and Surfaces A: Physicochemical and Engineering Aspects , vol. 587 , 124228 . https://doi.org/10.1016/j.colsurfa.2019.124228