Industrial production of colloidal lignin particles and biomass-based platform chemicals

dc.contributorAalto Universityen
dc.contributor.advisorSarwar, Golam, Dr., Aalto University, Finland
dc.contributor.authorBangalore Ashok, Rahul Prasad
dc.contributor.departmentKemian tekniikan ja metallurgian laitosfi
dc.contributor.departmentDepartment of Chemical and Metallurgical Engineeringen
dc.contributor.labPlant designen
dc.contributor.schoolKemian tekniikan korkeakoulufi
dc.contributor.schoolSchool of Chemical Technologyen
dc.contributor.supervisorOinas, Pekka, Prof., Aalto University, Department of Chemical and Metallurgical Engineering, Finland
dc.descriptionDefence is held on 22.4.2022 12:00 – 15:00
dc.description.abstractThe main goal of this doctoral research is the development of economically, technically feasible, sustainable, and profitable processes to produce valuable products from biomass. The lignin fraction is used to produce lignin-based adhesives and coatings which are more sustainable and eco-friendlier in comparison to the currently used phenol-formaldehyde based adhesives in the market. On the other hand, multiple valuable platform chemicals are produced using the cellulose and hemicellulose fractions for use in applications such as biofuels and solvents. Sustainable synthesis routes were identified, and techno-economic process models were developed to carry out process conceptualization, process simulation and modelling, process optimization and feasibility assessment. Discounted cash flow rate of return (DCFROR) analysis was performed to determine the cost of production/minimum selling prices of the biomass derived products. The process profitability was ascertained by using different criteria such as net present value (NPV), internal rate of return (IRR), payback period and return on investment. Sensitivity studies helped in understanding the impact of key process and economic parameters on the process and the risk involved in the project was gauged by carrying out uncertainty analysis using Monte Carlo simulations. The key findings of the dissertation are as follows: (1) A novel and sustainable approach for the economical industrial-scale production of colloidal lignin particles was conceptualized and developed. The CLPs produced could compete with petrochemical feedstock and ensure efficient way to utilize lignin in value-added applications capable of generating revenue; (2) A novel tubular reactor containing static mixing elements was designed and developed for the continuous processing of colloidal lignin particles. The tubular reactor produced CLPs with uniform particle diameter, high stability and enabled easy scalability for industrial use; (3) The techno-economics of furfural production from birch hydolysate liquor was investigated and biomass derived furfural could be manufactured at a competitive market price (4) An integrated biorefinery concept was conceptualized and developed to produce multiple platform chemicals such as GVL, 2-MTHF and 5-HMF from lignocellulosic biomass (spruce). The lignin and humins generated during the process were used for meeting the heating and electricity demands for the process, thereby making it self-sustaining, energy efficient and environmentally sustainable.en
dc.format.extent64 + app. 76
dc.identifier.isbn978-952-64-0721-0 (electronic)
dc.identifier.isbn978-952-64-0720-3 (printed)
dc.identifier.issn1799-4942 (electronic)
dc.identifier.issn1799-4934 (printed)
dc.identifier.issn1799-4934 (ISSN-L)
dc.opnKeiski, Riitta, Prof., University of Oulu, Finland
dc.opnHulteberg, Christian, Prof., Lund University, Sweden
dc.publisherAalto Universityen
dc.relation.haspart[Publication 1]: Ashok, R.P.B., Oinas, P., Lintinen, K., Sarwar, G., Kostiainen, M.A., Österberg, M. 2018. Techno-economic assessment for the large-scale production of colloidal lignin particles. Green Chemistry, 20(21), 4911- 4919. Full text in Acris/Aaltodoc: DOI: 10.1039/C8GC02805B
dc.relation.haspart[Publication 2]: Ashok, R.P.B., Xiao, Y., Lintinen, K., Oinas, P., Kostiainen, M.A., Österberg, M. 2020. Self-assembly of colloidal lignin particles in a continuous flow tubular reactor. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 587, 24228. Full text in Acris/Aaltodoc: DOI: 10.1016/j.colsurfa.2019.124228
dc.relation.haspart[Publication 3]: Millán, G.G., Ashok, R.P.B., Oinas, P., Llorca, J., Sixta, H. 2020. Furfural production from xylose and birch hydrolysate liquor in a biphasic system and techno-economic analysis. Biomass Conversion and Biorefinery, 1- 12. DOI: 10.1007/s13399-020-00702-4
dc.relation.haspart[Publication 4]: Ashok, R.P.B., Oinas, P., Forssell, Susanna. 2021. Techno-economic evaluation of a biorefinery to produce γ-valerolactone (GVL), 2-methyltetrahydrofuran (2-MTHF) and 5-hydroxymethylfurfural (5- HMF) from spruce. Under review. Renewable Energy
dc.relation.ispartofseriesAalto University publication series DOCTORAL THESESen
dc.revHulteberg, Christian, Prof., Lund University, Sweden
dc.revTanskanen, Juha, Prof., University of Oulu, Finland
dc.subject.keywordcolloidal lignin particlesen
dc.subject.keywordplatform chemicalsen
dc.subject.keywordtechno-economic assessmenten
dc.subject.keywordprocess modelingen
dc.titleIndustrial production of colloidal lignin particles and biomass-based platform chemicalsen
dc.typeG5 Artikkeliväitöskirjafi
dc.type.ontasotDoctoral dissertation (article-based)en
dc.type.ontasotVäitöskirja (artikkeli)fi
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