Industrial production of colloidal lignin particles and biomass-based platform chemicals

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School of Chemical Technology | Doctoral thesis (article-based) | Defence date: 2022-04-22
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Authors

Date

2022

Department

Kemian tekniikan ja metallurgian laitos
Department of Chemical and Metallurgical Engineering

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Mcode

Degree programme

Language

en

Pages

64 + app. 76

Series

Aalto University publication series DOCTORAL THESES, 34/2022

Abstract

The main goal of this doctoral research is the development of economically, technically feasible, sustainable, and profitable processes to produce valuable products from biomass. The lignin fraction is used to produce lignin-based adhesives and coatings which are more sustainable and eco-friendlier in comparison to the currently used phenol-formaldehyde based adhesives in the market. On the other hand, multiple valuable platform chemicals are produced using the cellulose and hemicellulose fractions for use in applications such as biofuels and solvents. Sustainable synthesis routes were identified, and techno-economic process models were developed to carry out process conceptualization, process simulation and modelling, process optimization and feasibility assessment. Discounted cash flow rate of return (DCFROR) analysis was performed to determine the cost of production/minimum selling prices of the biomass derived products. The process profitability was ascertained by using different criteria such as net present value (NPV), internal rate of return (IRR), payback period and return on investment. Sensitivity studies helped in understanding the impact of key process and economic parameters on the process and the risk involved in the project was gauged by carrying out uncertainty analysis using Monte Carlo simulations. The key findings of the dissertation are as follows: (1) A novel and sustainable approach for the economical industrial-scale production of colloidal lignin particles was conceptualized and developed. The CLPs produced could compete with petrochemical feedstock and ensure efficient way to utilize lignin in value-added applications capable of generating revenue; (2) A novel tubular reactor containing static mixing elements was designed and developed for the continuous processing of colloidal lignin particles. The tubular reactor produced CLPs with uniform particle diameter, high stability and enabled easy scalability for industrial use; (3) The techno-economics of furfural production from birch hydolysate liquor was investigated and biomass derived furfural could be manufactured at a competitive market price (4) An integrated biorefinery concept was conceptualized and developed to produce multiple platform chemicals such as GVL, 2-MTHF and 5-HMF from lignocellulosic biomass (spruce). The lignin and humins generated during the process were used for meeting the heating and electricity demands for the process, thereby making it self-sustaining, energy efficient and environmentally sustainable.

Description

Defence is held on 22.4.2022 12:00 – 15:00 https://aalto.zoom.us/j/66920855239

Supervising professor

Oinas, Pekka, Prof., Aalto University, Department of Chemical and Metallurgical Engineering, Finland

Thesis advisor

Sarwar, Golam, Dr., Aalto University, Finland

Keywords

colloidal lignin particles, biomass, platform chemicals, techno-economic assessment, process modeling

Other note

Parts

  • [Publication 1]: Ashok, R.P.B., Oinas, P., Lintinen, K., Sarwar, G., Kostiainen, M.A., Österberg, M. 2018. Techno-economic assessment for the large-scale production of colloidal lignin particles. Green Chemistry, 20(21), 4911- 4919.
    Full text in Acris/Aaltodoc: http://urn.fi/URN:NBN:fi:aalto-201811025593
    DOI: 10.1039/C8GC02805B View at publisher
  • [Publication 2]: Ashok, R.P.B., Xiao, Y., Lintinen, K., Oinas, P., Kostiainen, M.A., Österberg, M. 2020. Self-assembly of colloidal lignin particles in a continuous flow tubular reactor. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 587, 24228.
    Full text in Acris/Aaltodoc: http://urn.fi/URN:NBN:fi:aalto-202001171691
    DOI: 10.1016/j.colsurfa.2019.124228 View at publisher
  • [Publication 3]: Millán, G.G., Ashok, R.P.B., Oinas, P., Llorca, J., Sixta, H. 2020. Furfural production from xylose and birch hydrolysate liquor in a biphasic system and techno-economic analysis. Biomass Conversion and Biorefinery, 1- 12.
    DOI: 10.1007/s13399-020-00702-4 View at publisher
  • [Publication 4]: Ashok, R.P.B., Oinas, P., Forssell, Susanna. 2021. Techno-economic evaluation of a biorefinery to produce γ-valerolactone (GVL), 2-methyltetrahydrofuran (2-MTHF) and 5-hydroxymethylfurfural (5- HMF) from spruce. Under review. Renewable Energy

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https://urn.fi/URN:ISBN:978-952-64-0721-0

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[diss] Kemian tekniikan korkeakoulu / CHEM