Self-consistent study of electron confinement to metallic thin films on solid surfaces

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openAccess

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Journal Title

Journal ISSN

Volume Title

A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

Date

2005-05-10

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Mcode

Degree programme

Language

en

Pages

10
1-10

Series

Physical Review B, Volume 71, issue 20

Abstract

We present a method for density-functional modeling of metallic overlayers grown on a support. It offers a useful tool to study nanostructures, combining the power of self-consistent pseudopotential calculations with the simplicity of a one-dimensional approach. The model is illustrated for Pb layers grown on the Cu(111) surface. The analysis provides the strength of the electron confinement barriers in thin slabs with accuracy, supporting the interpretation of the quantum well state spectra measured by scanning tunneling spectroscopy. On the other hand, it offers a benchmark to check the simple analytical models commonly used in the literature to study metallic films on semiconducting or metallic surfaces. As a result, some deficiencies are detected in the applicability of those models, which often lead to an overestimation of the number of wetting layers. Finally, an improved formula is proposed.

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Keywords

Electron confinement, Quantum well states, Scanning tunneling spectroscopy

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Citation

Ogando , E , Zabala , N , Chulkov , E V & Puska , M J 2005 , ' Self-consistent study of electron confinement to metallic thin films on solid surfaces ' , Physical Review B , vol. 71 , no. 20 , 205401 , pp. 1-10 . https://doi.org/10.1103/PhysRevB.71.205401