Segmented Cell Design for Improved Factoring of Aging Effects in Dye Solar Cells

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© 2009 American Chemical Society (ACS). This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of Physical Chemistry C, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/jp902974v

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Volume Title

School of Science | A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

Date

2009

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Mcode

Degree programme

Language

en

Pages

1-19

Series

Journal of Physical Chemistry C, Volume 113, Issue 23

Abstract

A new segmented cell design was applied to study the aging of dye solar cell with stainless steel (StS) photoelectrode substrate, in particular the role of electrolyte in the degradation. Photovoltaic characterization indicated that StS photoelectrode cells are subjected to rapid (within hours or days) performance degradation that did not occur in the StS counter electrode cells. Other complementary techniques, open circuit voltage decay (OCVD) and electrochemical impedance spectroscopy (EIS), showed changes in the recombination at the photoelectrode/electrolyte interface. With the segmented cell method, we confirmed that the electrolyte was not contaminated by the StS nor was it subject to other significant changes related to the rapid degradation.

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Keywords

stainless steel, dye sensitized, solar cell, segmented

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Citation

Miettunen, Kati & Halme, Janne & Lund, Peter. 2009. Segmented Cell Design for Improved Factoring of Aging Effects in Dye Solar Cells. Journal of Physical Chemistry C. Volume 113, Issue 23. 10297-10302. ISSN 1932-7447 (printed). DOI: 10.1021/jp902974v.