Behavior of a magnetic impurity in graphene in the presence of a vacancy

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© 2012 American Physical Society (APS). This is the accepted version of the following article: Hu, F. M. & Gubernatis, J. E. & Lin, Hai-Qing & Li, Yan-Chao & Nieminen, Risto M. 2012. Behavior of a magnetic impurity in graphene in the presence of a vacancy. Physical Review B. Volume 85, Issue 11. 115442/1-5. ISSN 1550-235X (electronic). DOI: 10.1103/physrevb.85.115442, which has been published in final form at http://journals.aps.org/prb/abstract/10.1103/PhysRevB.85.115442.

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Volume Title

School of Science | A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

Date

2012

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Mcode

Degree programme

Language

en

Pages

115442/1-5

Series

Physical Review B, Volume 85, Issue 11

Abstract

With quantum Monte Carlo methods, we investigate the consequences of placing a magnetic adatom adjacent to a vacancy in a graphene sheet. We find that instead of the adatom properties depending on the energy of the adatom orbital, as in a single-impurity problem, they develop a dependence on the energy of the split localized state associated with the single-vacancy problem. Shifting the chemical potential through this experimentally more accessible energy scale reveals unique behavior in the spectral density, magnetic susceptibility, and the correlations of the adatom spin and charge with those of the conduction electrons. In general, the behavior of the adatom in the presence of a vacancy differs significantly from its behavior in the absence of a vacancy.

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Keywords

graphene sheets, magnetic impurities, vacancy, quantum Monte Carlo methods

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Citation

Hu, F. M. & Gubernatis, J. E. & Lin, Hai-Qing & Li, Yan-Chao & Nieminen, Risto M. 2012. Behavior of a magnetic impurity in graphene in the presence of a vacancy. Physical Review B. Volume 85, Issue 11. 115442/1-5. ISSN 1550-235X (electronic). DOI: 10.1103/physrevb.85.115442.