Effects of atomic layer deposition on the optical properties of two-dimensional transition metal dichalcogenide monolayers

Loading...
Thumbnail Image

Access rights

openAccess
publishedVersion

URL

Journal Title

Journal ISSN

Volume Title

A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

Major/Subject

Mcode

Degree programme

Language

en

Pages

9

Series

2D Materials, Volume 10, issue 4

Abstract

Two-dimensional semiconducting transition metal dichalcogenides (TMDs) have attracted significant interest due to their unique optoelectronic properties. More often, these materials are enclosed inside a dielectric layer that can work as an insulator for field-effect transistors. The insulating layer is typically grown with atomic layer deposition (ALD). Here, we study the effects on bare and hBN-covered monolayer MoS 2 and WSe 2 flakes with ALD TiO 2 films. Our results reveal a significant shift and decrease in intensity in photoluminescence and Raman signals of the monolayer TMDs. Further analysis suggests that these changes are caused by chemical doping, strain, and dielectric screening after the ALD. Our study not only sheds light on the impact of ALD on the properties of TMDs, but also indicates ALD can be an alternative method to engineer the doping, strain and dielectric environment for potential optoelectronics and photonics applications.

Description

| openaire: EC/H2020/834742/EU//ATOP

Other note

Citation

Turunen, M, Fernandez Pizarro, H, Akkanen, S-T, Seppänen, H & Sun, Z 2023, 'Effects of atomic layer deposition on the optical properties of two-dimensional transition metal dichalcogenide monolayers', 2D Materials, vol. 10, no. 4, 045018. https://doi.org/10.1088/2053-1583/acf1ad