Lyotropic liquid crystals and linear supramolecular polymers of end-functionalized oligosaccharides
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A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä
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Date
2019
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en
Pages
4
11739-11742
11739-11742
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Chemical Communications, Volume 55, issue 78
Abstract
We synthesized permethylated maltoheptaose oligosaccharides, whose both ends, untrivially, have been functionalized with supramolecular binders 2-ureido-4[1H]-pyrimidinones (UPy) after single ring-opening of β-cyclodextrin counterpart. In 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP), they show lyotropic liquid crystallinity. In the dried state they allow linear saccharide-based supramolecular polymers by UPy-dimerization.Description
| openaire: EC/H2020/742829/EU//DRIVEN
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Myllymäki, T T T, Guliyeva, A, Korpi, A, Kostiainen, M, Hynninen, V, Nonappa, N, Rannou, P, Ikkala, O & Halia, S 2019, ' Lyotropic liquid crystals and linear supramolecular polymers of end-functionalized oligosaccharides ', Chemical Communications, vol. 55, no. 78, pp. 11739-11742 . https://doi.org/10.1039/C9CC04715H