Fabrication of Polycaprolactone/nanocellulose composite based on Pickering emulsion template stabilized by lignin particles

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Journal Title

Journal ISSN

Volume Title

Perustieteiden korkeakoulu | Master's thesis

Date

2020-10-20

Department

Major/Subject

Advanced Materials for Innovation and Sustainability

Mcode

SCI3083

Degree programme

Master’s Programme in Advanced Materials for Innovation and Sustainability

Language

en

Pages

54+1

Series

Abstract

Increasing the need for evolution of sustainable products has recently driven huge interest to develop biobased composites as eco-friendly alternatives for petroleum-based materials. Cellulose nanofibril (CNF) reinforced composites have extensively shown great potential in this field due to their high abundance, renewability, biodegradability, and superior mechanical properties. However, their hydrophilic nature induced incompatibility with many hydrophobic polymer matrixes that has limited their use. In the present work, lignin nanoparticles stabilized Pickering emulsion template was introduced for the first time to incorporation of CNF into the polymer matrix for developing nanocomposite materials. The obtained biobased composite films exhibited proper mechanical properties that demonstrate the high potential in many fields such as packaging and biomedical applications. Additionally, comprehensive literature survey will be presented in this work including, the introduction of lignocellulosic biomass and its constituents, lignin structure, most important methods for extraction of lignin from lignocellulosic biomass, transforming lignin into colloidal particles, and evaluating its high value-added applications.

Description

Supervisor

Österberg, Monika

Thesis advisor

Grande, Rafael

Keywords

lignin valorization, colloidal lignin particles, pickering emulsion, cellulose nanofibril (CNF) reinforced composites

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