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Excitation-dependent fluorescence from atomic/molecular layer deposited sodium-uracil thin films

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A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

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en

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7

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Scientific Reports, Volume 7, pp. 1-7

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Atomic/molecular layer deposition (ALD/MLD) offers unique possibilities in the fabrication of inorganic-organic thin films with novel functionalities. Especially, incorporating nucleobases in the thin-film structures could open new avenues in the development of bio-electronic and photonic devices. Here we report an intense blue and widely excitation-dependent fluorescence in the visible region for ALD/MLD fabricated sodium-uracil thin films, where the crystalline network is formed from hydrogen-bonded uracil molecules linked via Na atoms. The excitation-dependent fluorescence is caused by the red-edge excitation shift (REES) effect taking place in the red-edge of the absorption spectrum, where the spectral relaxation occurs in continuous manner as demonstrated by the time-resolved measurements.

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| openaire: EC/FP7/339478/EU//LAYERENG-HYBMAT

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Pale, V, Giedraityte, Z, Chen, X, Lopez Acevedo, O, Tittonen, I & Karppinen, M 2017, 'Excitation-dependent fluorescence from atomic/molecular layer deposited sodium-uracil thin films', Scientific Reports, vol. 7, 6982, pp. 1-7. https://doi.org/10.1038/s41598-017-07456-6

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