Silver nanoparticles formation on fibres and potential for optical sensing

dc.contributorAalto-yliopistofi
dc.contributorAalto Universityen
dc.contributor.advisorArcot, Lokanathan
dc.contributor.authorXiang, Wenchao
dc.contributor.schoolKemian tekniikan korkeakoulufi
dc.contributor.supervisorRojas, Orlando
dc.date.accessioned2014-12-11T10:09:28Z
dc.date.available2014-12-11T10:09:28Z
dc.date.issued2014-12-02
dc.description.abstractSilver nanoparticles (AgNP) formation mediated by fibres in paper can be a promising process for optical sensing applications with high sensitivity and low cost. Thus, the aim of this thesis was to develop a paper-based sensor to quantify the concentration of analyte. The work focused on investigating the role of interactions between silver ions-cellulosic hydroxyl groups and analyte molecules in AgNP formation. A multilayer sensor module that included layers supporting silver ion precursor and ascorbic acid reducing agent was constructed. The effect of positional order of the sensor layers on AgNP formation was studied. UV-vis spectroscopy and SEM were used to characterize the AgNP plasmon effect and morphology, respectively. Initially, cationic (DDAB), anionic (SDS), and nonionic (Triton X) surfactants were used as model analytes carrying different electrostatic charges. Further investigation was performed with biomolecules including cholesterol, BSA, gamma-globulin. UV-vis absorption results of sensor modules with varied layer-order confirmed the pivotal role of cellulosic hydroxyls in AgNP nucleation and growth processes, which were characterized by the two typical plasmonic peaks located at short and long wavelengths (~420 and 500~600 nm, respectively). Compared with the nonionic and the surfactant-free conditions, the cationic and anionic surfactants yielded more uniform and reproducible results in terms of AgNP formation and respective plasmon signal. The investigation with cholesterol confirmed main findings with surfactants by revealing distinct blue shifts in the long wavelength plasmonic peaks. However, the results with BSA and gamma-globulin proteins were inconclusive due to the possible the interference of impurities or other causes not yet identified. The findings in this thesis not only are consistent with previous studies, but also highlight opportunities for sensor design based on AgNP formation process instead of traditional platforms based on pre-synthesized AgNP. Further work will be needed to understand the mechanism of blue shift caused by the analyte and to optimize its correlation with concentration in the presence of interfering substances.en
dc.format.extent56
dc.format.mimetypeapplication/pdfen
dc.identifier.urihttps://aaltodoc.aalto.fi/handle/123456789/14657
dc.identifier.urnURN:NBN:fi:aalto-201412113204
dc.language.isoenen
dc.locationPKfi
dc.programmeKEM - Kemian tekniikan koulutusohjelmafi
dc.programme.majorRenewable Materials Engineeringfi
dc.programme.mcodeKM3002fi
dc.rights.accesslevelopenAccess
dc.subject.keywordpaper sensoren
dc.subject.keywordsilver nanoparticlesen
dc.subject.keywordcellulose hydroxylen
dc.subject.keywordsurface plasmon resonanceen
dc.subject.keywordUV-vis absorptionen
dc.titleSilver nanoparticles formation on fibres and potential for optical sensingen
dc.typeG2 Pro gradu, diplomityöen
dc.type.okmG2 Pro gradu, diplomityö
dc.type.ontasotMaster's thesisen
dc.type.ontasotDiplomityöfi
dc.type.publicationmasterThesis
local.aalto.digifolderAalto_07455
local.aalto.idinssi50213
local.aalto.openaccessyes
Files
Original bundle
Now showing 1 - 1 of 1
No Thumbnail Available
Name:
master_Xiang_Wenchao_2014.pdf
Size:
2.62 MB
Format:
Adobe Portable Document Format