An Unprecedented Fully H–-Substituted Phosphate Hydride Sr5(PO4)3H Expanding the Apatite Family

dc.contributorAalto-yliopistofi
dc.contributorAalto Universityen
dc.contributor.authorMutschke, Alexanderen_US
dc.contributor.authorWylezich, Thomasen_US
dc.contributor.authorRitter, Clemensen_US
dc.contributor.authorKarttunen, Antti J.en_US
dc.contributor.authorKunkel, Nathalieen_US
dc.contributor.departmentDepartment of Chemistry and Materials Scienceen
dc.contributor.groupauthorInorganic Materials Modellingen
dc.contributor.organizationTechnische Universität Münchenen_US
dc.contributor.organizationInstitut Laue-Langevinen_US
dc.date.accessioned2020-09-11T06:30:30Z
dc.date.available2020-09-11T06:30:30Z
dc.date.issued2019-12-31en_US
dc.description.abstractThe apatite family is a mineral class that also contains the biologically very important hydroxyapatite. Here, we are reporting on the synthesis and characterization of a fully hydride-substituted strontium apatite, which could be obtained via mechanochemical synthesis and subsequent annealing treatment. The full substitution by hydride anions is proven by various methods, such as neutron powder diffraction of a deuterated sample Sr5(PO4)3D, as well 1H MAS solid state NMR combined with quantum chemical calculations, vibrational spectroscopy and elemental analysis. The present work expands the apatite family from the known halide and hydroxide apatites to the fully hydride-anion-substituted variant and is expected to open up a new field of materials containing coexistent phosphate and hydride anions.en
dc.description.versionPeer revieweden
dc.format.extent4
dc.format.extent5073-5076
dc.format.mimetypeapplication/pdfen_US
dc.identifier.citationMutschke, A, Wylezich, T, Ritter, C, Karttunen, A J & Kunkel, N 2019, ' An Unprecedented Fully H – -Substituted Phosphate Hydride Sr 5 (PO 4 ) 3 H Expanding the Apatite Family ', European Journal of Inorganic Chemistry, vol. 2019, no. 48, pp. 5073-5076 . https://doi.org/10.1002/ejic.201901151en
dc.identifier.doi10.1002/ejic.201901151en_US
dc.identifier.issn1434-1948
dc.identifier.issn1099-0682
dc.identifier.otherPURE UUID: 6c41d943-cc33-4fef-ada3-0167db684fc5en_US
dc.identifier.otherPURE ITEMURL: https://research.aalto.fi/en/publications/6c41d943-cc33-4fef-ada3-0167db684fc5en_US
dc.identifier.otherPURE LINK: http://www.scopus.com/inward/record.url?scp=85076725432&partnerID=8YFLogxKen_US
dc.identifier.otherPURE FILEURL: https://research.aalto.fi/files/51152572/ejic.201901151.pdfen_US
dc.identifier.urihttps://aaltodoc.aalto.fi/handle/123456789/46430
dc.identifier.urnURN:NBN:fi:aalto-202009115353
dc.language.isoenen
dc.publisherWILEY-BLACKWELL
dc.relation.ispartofseriesEuropean Journal of Inorganic Chemistryen
dc.rightsopenAccessen
dc.subject.keywordApatitesen_US
dc.subject.keywordHydridesen_US
dc.subject.keywordMechanochemical synthesisen_US
dc.subject.keywordMixed anionic compoundsen_US
dc.subject.keywordNeutron diffractionen_US
dc.subject.keywordStrontiumen_US
dc.titleAn Unprecedented Fully H–-Substituted Phosphate Hydride Sr5(PO4)3H Expanding the Apatite Familyen
dc.typeA1 Alkuperäisartikkeli tieteellisessä aikakauslehdessäfi
dc.type.versionpublishedVersion
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