A 1D Coordination Polymer of UF5 with HCN as a Ligand
Loading...
Access rights
openAccess
Journal Title
Journal ISSN
Volume Title
A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä
This publication is imported from Aalto University research portal.
View publication in the Research portal
View/Open full text file from the Research portal
Other link related to publication
View publication in the Research portal
View/Open full text file from the Research portal
Other link related to publication
Date
2017-01-05
Major/Subject
Mcode
Degree programme
Language
en
Pages
5
291-295
291-295
Series
CHEMISTRY: A EUROPEAN JOURNAL, Volume 23, issue 2
Abstract
β-Uranium(V) fluoride was reacted with liquid anhydrous hydrogen cyanide to obtain a 1D coordination polymer with the composition (Formula presented.) [UF5(HCN)2], (Formula presented.) [UF4/1F2/2- (HCN)2/1], revealed by single-crystal X-ray structure determination. The reaction system was furthermore studied by means of vibrational and NMR spectroscopy, as well as by quantum chemical calculations. The compound presents the first described polymeric HCN Lewis adduct and the first HCN adduct of a uranium fluoride.Description
Keywords
coordination polymer, cyanides, fluorides, uranium, X-ray diffraction
Other note
Citation
Scheibe , B , Rudel , S S , Buchner , M R , Karttunen , A J & Kraus , F 2017 , ' A 1D Coordination Polymer of UF 5 with HCN as a Ligand ' , CHEMISTRY: A EUROPEAN JOURNAL , vol. 23 , no. 2 , pp. 291-295 . https://doi.org/10.1002/chem.201605293
