Synthesis and Characterization of the Tetrafluoridochlorates(III) A[ClF4] (A = K, Rb, Cs)

dc.contributorAalto-yliopistofi
dc.contributorAalto Universityen
dc.contributor.authorScheibe, Benjaminen_US
dc.contributor.authorIvlev, Sergei I.en_US
dc.contributor.authorKarttunen, Antti J.en_US
dc.contributor.authorKraus, Florianen_US
dc.contributor.departmentDepartment of Chemistry and Materials Scienceen
dc.contributor.groupauthorInorganic Materials Modellingen
dc.contributor.organizationUniversity of Marburgen_US
dc.date.accessioned2020-06-01T06:50:27Z
dc.date.available2020-06-01T06:50:27Z
dc.date.issued2020-04-16en_US
dc.description.abstractSingle-crystalline tetrafluoridochlorates(III) A[ClF4] (A = K, Rb, Cs) were synthesized from solvolysis reactions of alkali metal fluorides in liquid chlorine trifluoride. The structures were examined by means of single-crystal X-ray diffraction. K[ClF4] crystallizes in the K[BrF4] structure type, whereas the Rb and Cs compounds crystallize in the Li[AuF4] structure type. The compounds were further characterized by Raman and IR spectroscopy. Solid-state quantum-chemical calculations with hybrid density functional methods reproduced the experimental structures and enabled the interpretation of the experimental Raman and IR spectra.en
dc.description.versionPeer revieweden
dc.format.extent6
dc.format.extent1319-1324
dc.format.mimetypeapplication/pdfen_US
dc.identifier.citationScheibe, B, Ivlev, S I, Karttunen, A J & Kraus, F 2020, ' Synthesis and Characterization of the Tetrafluoridochlorates(III) A[ClF 4 ] (A = K, Rb, Cs) ', European Journal of Inorganic Chemistry, vol. 2020, no. 14, pp. 1319-1324 . https://doi.org/10.1002/ejic.202000106en
dc.identifier.doi10.1002/ejic.202000106en_US
dc.identifier.issn1434-1948
dc.identifier.issn1099-0682
dc.identifier.otherPURE UUID: 0953def1-5815-4401-94d0-fc15b3c7b5c0en_US
dc.identifier.otherPURE ITEMURL: https://research.aalto.fi/en/publications/0953def1-5815-4401-94d0-fc15b3c7b5c0en_US
dc.identifier.otherPURE LINK: http://www.scopus.com/inward/record.url?scp=85081563957&partnerID=8YFLogxKen_US
dc.identifier.otherPURE FILEURL: https://research.aalto.fi/files/42952081/CHEM_Scheibe_et_al_2020_Synthesis_Characterization_EurJourInorg.pdfen_US
dc.identifier.urihttps://aaltodoc.aalto.fi/handle/123456789/44452
dc.identifier.urnURN:NBN:fi:aalto-202006013425
dc.language.isoenen
dc.publisherWILEY-BLACKWELL
dc.relation.ispartofseriesEuropean Journal of Inorganic Chemistryen
dc.relation.ispartofseriesVolume 2020, issue 14en
dc.rightsopenAccessen
dc.subject.keywordChlorineen_US
dc.subject.keywordDensity Functional Theory Calculationsen_US
dc.subject.keywordFluorineen_US
dc.subject.keywordInterhalogen Compoundsen_US
dc.titleSynthesis and Characterization of the Tetrafluoridochlorates(III) A[ClF4] (A = K, Rb, Cs)en
dc.typeA1 Alkuperäisartikkeli tieteellisessä aikakauslehdessäfi
dc.type.versionpublishedVersion
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