White-light emitting multi-lanthanide terephthalate thin films by atomic/molecular layer deposition

dc.contributorAalto-yliopistofi
dc.contributorAalto Universityen
dc.contributor.authorGhazy, Amren_US
dc.contributor.authorLastusaari, Mikaen_US
dc.contributor.authorKarppinen, Maariten_US
dc.contributor.departmentDepartment of Chemistry and Materials Scienceen
dc.contributor.groupauthorInorganic Materials Chemistryen
dc.contributor.organizationUniversity of Turkuen_US
dc.date.accessioned2023-05-08T04:30:38Z
dc.date.available2023-05-08T04:30:38Z
dc.date.issued2023-04-28en_US
dc.descriptionFunding Information: We acknowledge the funding from the Academy of Finland (PREIN Flagship), and the use of the RawMatTERS Finland Infrastructure (RAMI) at Aalto University. A. G. acknowledges Jenny & Antti Wihuri foundation for financial support. Publisher Copyright: © 2023 The Royal Society of Chemistry.
dc.description.abstractPrecisely composition-tuned white-light-emissive lanthanide-organic thin films are fabricated using the combined atomic/molecular layer deposition (ALD/MLD) technique. The emission colour characteristics are comparable (and even exceeding) to those measured for commercial incandescent bulbs, fluorescent tubes and LED lamps. The films are composed of up to four lanthanide species (La, Er, Tb, and Eu) and terephthalate as the organic linker molecule. Terephthalate plays multiple roles in the films, as it not only brings mechanical flexibility to the films and defines the distance between the lanthanide ions, but also shows upon UV excitation UV/blue broad-band emission around 300-450 nm. This excitation energy was found to be efficiently transferred to the Er3+ ions, such that the emission could be shifted to the longer wavelengths. Then, Tb and Eu provide the green and red emissions, such that the films in overall show warm white light emission. Finally, using a three-layer composition to control the distribution of the Ln dopants, the emission intensity was increased fourfold.en
dc.description.versionPeer revieweden
dc.format.extent5331-5336
dc.format.mimetypeapplication/pdfen_US
dc.identifier.citationGhazy, A, Lastusaari, M & Karppinen, M 2023, ' White-light emitting multi-lanthanide terephthalate thin films by atomic/molecular layer deposition ', Journal of Materials Chemistry C, vol. 11, no. 16, pp. 5331-5336 . https://doi.org/10.1039/d3tc00464cen
dc.identifier.doi10.1039/d3tc00464cen_US
dc.identifier.issn2050-7526
dc.identifier.issn2050-7534
dc.identifier.otherPURE UUID: 56e3fb0d-8054-4c67-ba54-86045a9f97c2en_US
dc.identifier.otherPURE ITEMURL: https://research.aalto.fi/en/publications/56e3fb0d-8054-4c67-ba54-86045a9f97c2en_US
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dc.identifier.otherPURE FILEURL: https://research.aalto.fi/files/107486231/CHEM_Ghazy_et_al_White_light_emitting_2023_J_Mater_Chem_C.pdfen_US
dc.identifier.urihttps://aaltodoc.aalto.fi/handle/123456789/120639
dc.identifier.urnURN:NBN:fi:aalto-202305082981
dc.language.isoenen
dc.publisherRoyal Society of Chemistry
dc.relation.ispartofseriesJournal of Materials Chemistry Cen
dc.relation.ispartofseriesVolume 11, issue 16en
dc.rightsopenAccessen
dc.titleWhite-light emitting multi-lanthanide terephthalate thin films by atomic/molecular layer depositionen
dc.typeA1 Alkuperäisartikkeli tieteellisessä aikakauslehdessäfi
dc.type.versionpublishedVersion
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