Trends in Carbon, Oxygen, and Nitrogen Core in the X-ray Absorption Spectroscopy of Carbon Nanomaterials : A Guide for the Perplexed

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dc.contributorAalto-yliopistofi
dc.contributorAalto Universityen
dc.contributor.authorSainio, Samien_US
dc.contributor.authorWester, Niklasen_US
dc.contributor.authorAarva, Anjaen_US
dc.contributor.authorTitus, Charles J.en_US
dc.contributor.authorNordlund, Dennisen_US
dc.contributor.authorKauppinen, Esko I.en_US
dc.contributor.authorLeppänen, Ellien_US
dc.contributor.authorPalomäki, Tommien_US
dc.contributor.authorKoehne, Jessica E.en_US
dc.contributor.authorPitkänen, Ollien_US
dc.contributor.authorKordas, Krisztianen_US
dc.contributor.authorKim, Mariaen_US
dc.contributor.authorLipsanen, Harrien_US
dc.contributor.authorMozetič, Miranen_US
dc.contributor.authorCaro, Miguel A.en_US
dc.contributor.authorMeyyappan, M.en_US
dc.contributor.authorKoskinen, Jarien_US
dc.contributor.authorLaurila, Tomien_US
dc.contributor.departmentDepartment of Chemistry and Materials Scienceen
dc.contributor.departmentDepartment of Electrical Engineering and Automationen
dc.contributor.departmentDepartment of Applied Physicsen
dc.contributor.departmentDepartment of Electronics and Nanoengineeringen
dc.contributor.groupauthorPhysical Characteristics of Surfaces and Interfacesen
dc.contributor.groupauthorMicrosystems Technologyen
dc.contributor.groupauthorNanoMaterialsen
dc.contributor.groupauthorHarri Lipsanen Groupen
dc.contributor.organizationStanford Universityen_US
dc.contributor.organizationNASA Ames Research Centeren_US
dc.contributor.organizationUniversity of Ouluen_US
dc.contributor.organizationJožef Stefan Instituteen_US
dc.date.accessioned2021-01-25T10:15:07Z
dc.date.available2021-01-25T10:15:07Z
dc.date.issued2021-01-14en_US
dc.description| openaire: EC/H2020/824070/EU//CONNECT
dc.description.abstractSuccessful deployment of carbon nanomaterials in many applications, such as sensing, energy storage, and catalysis, relies on the selection, synthesis, and tailoring of the surface properties. Predictive analysis of the behavior is difficult without detailed knowledge of the differences between various carbon nanomaterials and their surface functionalization, thus leaving the selection process to traditional trial-and-error work. The present characterization fills this knowledge gap for carbon nanomaterial surface properties with respect to chemical states and functionalization. We present an overview of the chemical trends that can be extracted from soft X-ray absorption spectroscopy (XAS) spectra on an extended set of nonideal carbon nanomaterials as a function of sp2 bonded carbon and bond ordering. In particular, the surface chemical state, the presence of long-range order in the carbon matrix, and a qualitative estimation of the amount of oxygen and nitrogen and their respective functional group formation on the material surface, together with the detailed material fabrication parameters, are reported. The results expand our understanding of carbon nanomaterial functionalization, which can support material selection in practice, provided that the specifications of the application are known.en
dc.description.versionPeer revieweden
dc.format.extent16
dc.format.mimetypeapplication/pdfen_US
dc.identifier.citationSainio, S, Wester, N, Aarva, A, Titus, C J, Nordlund, D, Kauppinen, E I, Leppänen, E, Palomäki, T, Koehne, J E, Pitkänen, O, Kordas, K, Kim, M, Lipsanen, H, Mozetič, M, Caro, M A, Meyyappan, M, Koskinen, J & Laurila, T 2021, ' Trends in Carbon, Oxygen, and Nitrogen Core in the X-ray Absorption Spectroscopy of Carbon Nanomaterials : A Guide for the Perplexed ', Journal of Physical Chemistry C, vol. 125, no. 1, pp. 973-988 . https://doi.org/10.1021/acs.jpcc.0c08597en
dc.identifier.doi10.1021/acs.jpcc.0c08597en_US
dc.identifier.issn1932-7447
dc.identifier.issn1932-7455
dc.identifier.otherPURE UUID: 912456a7-2cce-445c-8218-8640f10938eden_US
dc.identifier.otherPURE ITEMURL: https://research.aalto.fi/en/publications/912456a7-2cce-445c-8218-8640f10938eden_US
dc.identifier.otherPURE LINK: http://www.scopus.com/inward/record.url?scp=85099024106&partnerID=8YFLogxKen_US
dc.identifier.otherPURE FILEURL: https://research.aalto.fi/files/55254396/acs.jpcc.0c08597.pdfen_US
dc.identifier.urihttps://aaltodoc.aalto.fi/handle/123456789/102209
dc.identifier.urnURN:NBN:fi:aalto-202101251519
dc.language.isoenen
dc.publisherAMERICAN CHEMICAL SOCIETY
dc.relationinfo:eu-repo/grantAgreement/EC/H2020/824070/EU//CONNECTen_US
dc.relation.ispartofseriesJournal of Physical Chemistry Cen
dc.rightsopenAccessen
dc.titleTrends in Carbon, Oxygen, and Nitrogen Core in the X-ray Absorption Spectroscopy of Carbon Nanomaterials : A Guide for the Perplexeden
dc.typeA1 Alkuperäisartikkeli tieteellisessä aikakauslehdessäfi
dc.type.versionpublishedVersion
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