Evidence for valence fluctuation of Fe in Sr_(2)FeMoO_(6-w) double perovskite
| dc.contributor | Aalto-yliopisto | fi |
| dc.contributor | Aalto University | en |
| dc.contributor.author | Linden, J. | |
| dc.contributor.author | Yamamoto, T. | |
| dc.contributor.author | Karppinen, M. | |
| dc.contributor.author | Yamauchi, H. | |
| dc.contributor.author | Pietari, T. | |
| dc.contributor.department | Department of Chemistry | en |
| dc.date.accessioned | 2018-05-22T14:32:50Z | |
| dc.date.available | 2018-05-22T14:32:50Z | |
| dc.date.issued | 2000 | |
| dc.description.abstract | In this letter evidence for the formation of a valence-fluctuation state of iron, formally denoted as Fe2.5+, is presented. The system under study is the Sr2FeMoO6−w double perovskite, known for exhibiting a very large magnetoresistance. Samples of Sr2FeMoO6−w were synthesized by means of an encapsulation technique utilizing an Fe getter technique and characterized by 57Fe Mössbauer spectroscopy. From 5 K to room temperature the Mössbauer spectrum is dominated by a component with hyperfine parameter values between those expected for high-spin Fe3+ and high-spin Fe2+. | en |
| dc.description.version | Peer reviewed | en |
| dc.format.extent | 2925-2927 | |
| dc.format.mimetype | application/pdf | |
| dc.identifier.citation | Linden , J , Yamamoto , T , Karppinen , M , Yamauchi , H & Pietari , T 2000 , ' Evidence for valence fluctuation of Fe in Sr_(2)FeMoO_(6-w) double perovskite ' , Applied Physics Letters , vol. 76 , no. 20 , pp. 2925-2927 . https://doi.org/10.1063/1.126518 | en |
| dc.identifier.doi | 10.1063/1.126518 | |
| dc.identifier.issn | 0003-6951 | |
| dc.identifier.issn | 1077-3118 | |
| dc.identifier.other | PURE UUID: 328549ff-81fb-4601-ac52-358b8c884517 | |
| dc.identifier.other | PURE ITEMURL: https://research.aalto.fi/en/publications/328549ff-81fb-4601-ac52-358b8c884517 | |
| dc.identifier.other | PURE FILEURL: https://research.aalto.fi/files/14765180/1.126518.pdf | |
| dc.identifier.uri | https://aaltodoc.aalto.fi/handle/123456789/30838 | |
| dc.identifier.urn | URN:NBN:fi:aalto-201805222278 | |
| dc.language.iso | en | en |
| dc.relation.ispartofseries | APPLIED PHYSICS LETTERS | en |
| dc.relation.ispartofseries | Volume 76, issue 20 | en |
| dc.rights | openAccess | en |
| dc.subject.keyword | superconductor | |
| dc.title | Evidence for valence fluctuation of Fe in Sr_(2)FeMoO_(6-w) double perovskite | en |
| dc.type | A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä | fi |
| dc.type.version | publishedVersion |
