DNA‐Engineered Hydrogels with Light‐Adaptive Plasmonic Responses

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A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

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en

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10

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Advanced Functional Materials, Volume 32, issue 37

Abstract

Orientational control of anisotropic plasmonic nanoparticles is an attractive proposition to generate dynamic plasmonic responses. Particularly, the use of light as a stimulus to modulate the orientation is extremely useful owing to its spatiotemporal operative ability. This work showcases a light-mediated approach to tune the orientational features of gold nanorods in DNA-engineered hydrogel materials. The strategy relies on the use of visible-light-induced photothermal effects to cause deformation of the hydrogel matrix, resulting in temperature-controlled polarization-dependent optical responses whose anisotropy features are highly adaptive to the nature of DNA crosslinks. The visible-light-mediated approach showcased here can open novel avenues to create dynamic light-responsive materials with reconfigurable plasmonic responses.

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| openaire: EC/H2020/101030869/EU//ROBOT Sensing

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Ryssy, J, Lehtonen, A, Loo, J, Nguyen, K, Seitsonen, J, Huang, Y, Narasimhan, B N, Pokki, J, Kuzyk, A & Manuguri, S 2022, 'DNA‐Engineered Hydrogels with Light‐Adaptive Plasmonic Responses', Advanced Functional Materials, vol. 32, no. 37, 2201249. https://doi.org/10.1002/adfm.202201249