Model Studies Towards Alternative Cross-Linking of Unsaturated Polyesters

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A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

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en

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Letters in Organic Chemistry, Volume 2, pp. 74-76

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Fumaric and maleic acid esters are functionalised with propargylamine. A subsequent Pd/Cu-catalysed oxidative homo-coupling of two alkyne moieties yields the corresponding dimers. Hence, a model of an unsaturated polyester chain is cross-linked in a welldefined, metal-mediated reaction in a very high yield.

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Straub, T, Brunner, M & Koskinen, A M P 2005, 'Model Studies Towards Alternative Cross-Linking of Unsaturated Polyesters', Letters in Organic Chemistry, vol. 2, pp. 74-76. https://doi.org/10.2174/1570178053399868