A Fluoroponytailed NHC–Silver Complex Formed from Vinyl-imidazolium/AgNO3 under Aqueous– Ammoniacal Conditions

dc.contributorAalto-yliopistofi
dc.contributorAalto Universityen
dc.contributor.authorPartl, Gabrielen_US
dc.contributor.authorRauter, Marcusen_US
dc.contributor.authorFliri, Lukasen_US
dc.contributor.authorGelbrich, Thomasen_US
dc.contributor.authorKreutz, Christophen_US
dc.contributor.authorMüller, Thomasen_US
dc.contributor.authorKahlenberg, Volkeren_US
dc.contributor.authorNerdinger, Svenen_US
dc.contributor.authorSchottenberger, Herwigen_US
dc.contributor.departmentDepartment of Bioproducts and Biosystemsen
dc.contributor.groupauthorBiopolymer Chemistry and Engineeringen
dc.contributor.organizationUniversity of Innsbrucken_US
dc.contributor.organizationInfineon Technologies Austria AGen_US
dc.contributor.organizationNovartisen_US
dc.date.accessioned2022-08-10T08:22:43Z
dc.date.available2022-08-10T08:22:43Z
dc.date.issued2022-07-01en_US
dc.descriptionPublisher Copyright: © 2022 by the authors. Licensee MDPI, Basel, Switzerland.
dc.description.abstract3-(1H,1H,2H,2H-Perfluorooctyl)-1-vinylimidazolium chloride [2126844–17–3], a strong fluorosurfactant with remarkably high solubility in water, was expediently converted into the respective doubly NHC-complexed silver salt with nitrate as counter ion in quantitative yield. Due to its vinyl substituents, [bis(3-(1H,1H,2H,2H-perfluorooctyl)-1-vinylimidazol-2-ylidene)silver(I)] nitrate, Ag(FNHC)2NO3, represents a polymerizable N-heterocyclic carbene transfer reagent, thus potentially offering simple and robust access to coordination polymers with crosslinking metal bridges. The compound was characterized by infrared and NMR spectroscopy, mass spectrometry as well as elemental analysis, and supplemented by X-ray single-crystal structure determination. It crystallizes in the monoclinic crystal system in the space group P21/c. With 173.3◦, the geometry of the Ag-carbene bridge deviates slightly from linearity. The disordered perfluoroalkyl side chains exhibit a helical conformation.en
dc.description.versionPeer revieweden
dc.format.mimetypeapplication/pdfen_US
dc.identifier.citationPartl, G, Rauter, M, Fliri, L, Gelbrich, T, Kreutz, C, Müller, T, Kahlenberg, V, Nerdinger, S & Schottenberger, H 2022, ' A Fluoroponytailed NHC–Silver Complex Formed from Vinyl-imidazolium/AgNO 3 under Aqueous– Ammoniacal Conditions ', Molecules, vol. 27, no. 13, 4137 . https://doi.org/10.3390/molecules27134137en
dc.identifier.doi10.3390/molecules27134137en_US
dc.identifier.issn1420-3049
dc.identifier.otherPURE UUID: 99a25996-d9ee-4f20-8fbc-1bf81de6420den_US
dc.identifier.otherPURE ITEMURL: https://research.aalto.fi/en/publications/99a25996-d9ee-4f20-8fbc-1bf81de6420den_US
dc.identifier.otherPURE LINK: http://www.scopus.com/inward/record.url?scp=85133465422&partnerID=8YFLogxKen_US
dc.identifier.otherPURE FILEURL: https://research.aalto.fi/files/85850530/CHEM_Partl_et_al_A_Fluoroponytailed_NHC_Silver_Complex_2022_Molecules.pdfen_US
dc.identifier.urihttps://aaltodoc.aalto.fi/handle/123456789/115850
dc.identifier.urnURN:NBN:fi:aalto-202208104672
dc.language.isoenen
dc.publisherMDPI AG
dc.relation.ispartofseriesMoleculesen
dc.relation.ispartofseriesVolume 27, issue 13en
dc.rightsopenAccessen
dc.subject.keywordcationic fluorosurfactanten_US
dc.subject.keywordcrosslinkeren_US
dc.subject.keywordfluoroponytailen_US
dc.subject.keywordN-heterocyclic carbeneen_US
dc.subject.keywordsilveren_US
dc.titleA Fluoroponytailed NHC–Silver Complex Formed from Vinyl-imidazolium/AgNO3 under Aqueous– Ammoniacal Conditionsen
dc.typeA1 Alkuperäisartikkeli tieteellisessä aikakauslehdessäfi
dc.type.versionpublishedVersion

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