Unsupported electrospun membrane for water desalination using direct contact membrane distillation

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A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

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en

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15

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Journal of Applied Polymer Science, Volume 138, issue 7

Abstract

In this project, an unsupported electrospun poly(vinylidene fluoride)-co-hexafluoropropylene (PVDF-HFP) membrane was used for water desalination using direct contact membrane distillation (DCMD). The membrane was electrospun using a laboratory-scale machine with multiple nozzles that was developed in-house. Critical process parameters, including the applied voltage and polymer concentration, were optimized to obtain bead-free electrospun membranes with fiber diameters less than 300 nm. To improve the membrane thermal stability and performance, the selected electrospun membrane was heat-pressed at 160°C. The untreated and heat-pressed membranes were tested in a DCMD setup at different feed temperatures (60, 70, and 80°C) and feed flow rates (0.4, 0.6, and 0.8 L/min), while maintaining the permeate temperature and flow rate at 20°C and 0.2 L/min, respectively. The modified electrospun membrane exhibited a very high permeate flux (>37.5 kg/m2/h) and a salt rejection rate of 99.99% at a feed temperature of 70°C. The performance of the heat-pressed unsupported PVDF-HFP electrospun membrane was nearly identical to a commercially available polytetrafluoroethylene (PTFE) supported membrane. These promising results demonstrate that relatively low-cost electrospun membranes can be easily produced and successfully used in DCMD to minimize the capital cost and increase the energy efficiency of the process.

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Jalloul, G, Hashem, M H, Tehrani-Bagha, A R, Ahmad, M N & Abu Tarboush, B J 2021, 'Unsupported electrospun membrane for water desalination using direct contact membrane distillation', Journal of Applied Polymer Science, vol. 138, no. 7, 49861. https://doi.org/10.1002/app.49861