Mechanism of selective gold extraction from multi-metal chloride solutions by electrodeposition-redox replacement
Loading...
Access rights
openAccess
publishedVersion
URL
Journal Title
Journal ISSN
Volume Title
A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä
This publication is imported from Aalto University research portal.
View publication in the Research portal (opens in new window)
View/Open full text file from the Research portal (opens in new window)
Other link related to publication (opens in new window)
View publication in the Research portal (opens in new window)
View/Open full text file from the Research portal (opens in new window)
Other link related to publication (opens in new window)
Date
Major/Subject
Mcode
Degree programme
Language
en
Pages
11
Series
Green Chemistry, Volume 22, issue 11, pp. 3615-3625
Abstract
The electrodeposition-redox replacement (EDRR) process is a promising method for a selective extraction of minor metals from complex mixtures. When it is performed in a benign medium (such as sodium chloride solution or deep eutectic solvent), the EDRR method provides a non-toxic alternative for a conventional cyanide-based process. The detailed reaction mechanisms of the EDRR in Cu–Au systems, as well as the effect of the reaction medium are elucidated in this article. Electrogravimetric studies show that the EDRR process comprises three distinct stages: (1) deposition of Cu at a constant applied potential; (2) dissolution of deposited Cu at open circuit conditions in reaction with dissolved species in solution; (3) reduction of Au to elemental form in reaction with various Cu species. It is discovered that the recovery of Au takes place surprisingly via both the redox replacement between Cu and Au at the surface and the homogeneous Au reduction by Cu(I) species in solution. Both of these reaction pathways are facilitated by open circuit conditions (redox replacement step) between electrodeposition cycles and the utilization of other sacrificial elements in the solution is crucial. The use of aqueous chloride solution is advantageous over 1 : 2 ChCl : EG for the increased Au recovery (94.4%) and the purity of the product (93.7%), although it consumes slightly more electricity. Therefore, the EDRR enables energy and resource efficient selective extraction of Au from multi-metal industrial solutions even when it is present at low concentrations.Description
| openaire: EC/H2020/721385/EU//SOCRATES
Other note
Citation
Korolev, I, Spathariotis, S, Yliniemi, K, Wilson, B P, Abbott, A & Lundström, M 2020, 'Mechanism of selective gold extraction from multi-metal chloride solutions by electrodeposition-redox replacement', Green Chemistry, vol. 22, no. 11, pp. 3615-3625. https://doi.org/10.1039/D0GC00985G