X-ray reflectivity characterization of atomic layer deposition Al2O3/TiO2 nanolaminates with ultrathin bilayers

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© 2014 American Vacuum Society. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Vacuum Society. The following article appeared in Journal of Vacuum Science & Technology A and may be found at http://scitation.aip.org/content/avs/journal/jvsta

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Journal Title

Journal ISSN

Volume Title

School of Electrical Engineering | A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

Date

2014

Department

Mikro- ja nanotekniikan laitos
Department of Micro and Nanosciences

Major/Subject

Mcode

Degree programme

Language

en

Pages

01A111/1-4

Series

Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Volume 32, Issue 1

Abstract

Nanolaminate structures have many prospective uses in mechanical, electrical, and optical applications due to the wide selection of materials and precise control over layer thicknesses. In this work, ultrathin Al2O3/TiO2 nanolaminate structures deposited by atomic layer deposition from Me3Al, TiCl4, and H2O precursors with intended bilayer thicknesses ranging from 0.1 to 50 nm were characterized by x-ray reflectivity (XRR) measurements. The measurements were simulated to obtain values for thickness, density, and roughness of constituting layers. XRR analysis shows that the individual layers within the nanolaminate remain discrete for bilayers as thin as 0.8 nm. Further reduction in bilayer thickness produces a composite of the two materials.

Description

Keywords

ozone, superlattices, atomic layer deposition, reflectivity, nanostructures

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Citation

Sintonen, Sakari & Ali, Saima & Ylivaara, Oili M. E. & Puurunen, Riikka L. & Lipsanen, Harri. 2014. X-ray reflectivity characterization of atomic layer deposition Al2O3/TiO2 nanolaminates with ultrathin bilayers. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films. Volume 32, Issue 1. P. 01A111/1-4. ISSN 0734-2101 (printed). DOI: 10.1116/1.4833556.