NOUF6 Revisited

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openAccess

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Journal Title

Journal ISSN

Volume Title

A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

Date

2016-07-14

Major/Subject

Mcode

Degree programme

Language

en

Pages

12145–12153

Series

CHEMISTRY: A EUROPEAN JOURNAL, Volume 22, issue 34

Abstract

We have synthesized NOUF6 by direct reaction of NO with UF6 in anhydrous HF (aHF). Based on the unit cell volume and powder diffraction data, the compound was previously reported to be isotypic to O2PtF6, however, detailed structural data, such as the atom positions and all information that can be derived from those, were unavailable. We have therefore investigated the compound by using single-crystal and powder X-ray diffraction, IR, Raman, NMR, EPR, and photoluminescence spectroscopy, magnetic measurements, as well as chemical analysis, density determination, and quantum chemical calculations.

Description

Keywords

Anhydrous hydrogen fluoride, Fluorine, Hexafluoridouranate(V), Uranium, X-ray diffraction

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Citation

Scheibe , B , Lippert , S , Rudel , S S , Buchner , M R , Burghaus , O , Pietzonka , C , Koch , M , Karttunen , A J & Kraus , F 2016 , ' NOUF 6 Revisited : A Comprehensive Study of a Hexafluoridouranate(V) Salt ' , CHEMISTRY: A EUROPEAN JOURNAL , vol. 22 , no. 34 , pp. 12145–12153 . https://doi.org/10.1002/chem.201602265