Atomic Structure of a Spinel-Like Transition Al2O3(100) Surface

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© 2014 American Physical Society (APS). This is the accepted version of the following article: Jensen, Thomas N. ; Meinander, Kristoffer ; Helveg, Stig ; Foster, Adam S. ; Kulju, Sampo ; Musso, Tiziana ; Lauritsen, Jeppe V. 2014. Atomic Structure of a Spinel-Like Transition Al2O3(100) Surface. Physical Review Letters. Volume 113, Issue 10. 106103/1-5. ISSN 0031-9007 (printed). DOI: 10.1103/physrevlett.113.106103, which has been published in final form at http://journals.aps.org/prl/abstract/10.1103/PhysRevLett.113.106103

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Journal Title

Journal ISSN

Volume Title

School of Science | A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

Date

2014

Major/Subject

Mcode

Degree programme

Language

en

Pages

106103/1-5

Series

Physical Review Letters, Volume 113, Issue 10

Abstract

We study a crystalline epitaxial alumina thin film with the characteristics of a spinel-type transition Al2O3(100)surface by using atom-resolved noncontact atomic force microscopy and density functional theory. It is shown that the films are terminated by an Al-O layer rich in Al vacancies, exhibiting a strong preference for surface hydroxyl group formation in two configurations. The transition alumina films are crystalline and perfectly stable in ambient atmospheres, a quality which is expected to open the door to new fundamental studies of the surfaces of transition aluminas.

Description

Keywords

AFM, oxides, alumina thin films

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Citation

Jensen, Thomas N. & Meinander, Kristoffer & Helveg, Stig & Foster, Adam S. & Kulju, Sampo & Musso, Tiziana & Lauritsen, Jeppe V. 2014. Atomic Structure of a Spinel-Like Transition Al2O3(100) Surface. Physical Review Letters. Volume 113, Issue 10. 106103/1-5. ISSN 0031-9007 (printed). DOI: 10.1103/physrevlett.113.106103.