Mesophase characteristics of cellulose nanocrystal films prepared from electrolyte suspensions
Loading...
Access rights
openAccess
acceptedVersion
URL
Journal Title
Journal ISSN
Volume Title
A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä
This publication is imported from Aalto University research portal.
View publication in the Research portal (opens in new window)
View/Open full text file from the Research portal (opens in new window)
Other link related to publication (opens in new window)
View publication in the Research portal (opens in new window)
View/Open full text file from the Research portal (opens in new window)
Other link related to publication (opens in new window)
Date
Department
Major/Subject
Mcode
Degree programme
Language
en
Pages
12
Series
Journal of Colloid and Interface Science, Volume 599, pp. 207-218
Abstract
Cellulose nanocrystals (CNCs) exhibit a cholesteric mesophase above a critical concentration in aqueous suspensions. Above this concentration, CNCs self-organize into left-handed helicoidal structures that can be preserved in dried, stratified films. In this systematic study, we have prepared optically-active CNC films cast from different electrolyte suspensions and investigated, via circular dichroism and other techniques, the effects of counterion type (six mono/divalent salts, including those responsible for promoting “salting-out” and “salting-in” in the Hofmeister series) and ionic strength on mesomorphic behavior and cholesteric arrangement. The presence of electrolytes influences CNC colloidal stability by compressing the electric double layer and altering interactions among neighboring CNCs and water, thereby affecting the extent to which the CNCs form a mesophase. Interestingly, mesomorphic behavior and CNC alignment appear to be sensitive to cationic radius and charge valence, in which case the optical properties of CNC films can be adjusted for targeted sustainable applications. Such heuristic rules can be valuable for predicting the stability and characteristics of CNC microstructure in designer coatings and thin films prepared by introducing suitable cations prior to film formation.Description
Funding Information: This work was supported by the Eastman Chemical Company at North Carolina State University and was performed, in part, at the North Carolina State University Molecular Education, Technology and Research Innovation Center (METRIC) and Analytical Instrumentation Facility (AIF), the latter of which is supported by the State of North Carolina and the National Science Foundation (award number ECCS-1542015 ). The AIF is a member of the North Carolina Research Triangle Nanotechnology Network (RTNN), a site in the National Nanotechnology Coordinated Infrastructure (NNCI). We also thank one of the reviewers for insightful comments and recommendations. Publisher Copyright: © 2021 Elsevier Inc. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.
Other note
Citation
Jin, S A, Facchine, E G, Khan, S A, Rojas, O J & Spontak, R J 2021, 'Mesophase characteristics of cellulose nanocrystal films prepared from electrolyte suspensions', Journal of Colloid and Interface Science, vol. 599, pp. 207-218. https://doi.org/10.1016/j.jcis.2021.04.071