Lithium Aryloxide Thin Films with Guest-Induced Structural Transformation by ALD/MLD

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openAccess

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Journal Title

Journal ISSN

Volume Title

A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

Date

2017

Major/Subject

Mcode

Degree programme

Language

en

Pages

5
2988 – 2992

Series

CHEMISTRY: A EUROPEAN JOURNAL

Abstract

Crystalline Li-organic thin films are grown with the atomic/molecular layer deposition (ALD/MLD) technique from lithium hexamethyldisilazide and hydroquinone. The as-deposited films are found to undergo a reversible structural transformation upon exposure to ambient humid air. According to density functional theory calculations, the guest-induced transformation may be related to an unsaturated Li site in the crystal structure.

Description

| openaire: EC/FP7/339478/EU//LAYERENG-HYBMAT

Keywords

Atomic layer deposition, Coordination polymer, Lithium organic hybrid, Molecular layer deposition, Thin film

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Citation

Nisula, M, Linnera, J, Karttunen, A J & Karppinen, M 2017, ' Lithium Aryloxide Thin Films with Guest-Induced Structural Transformation by ALD/MLD ', CHEMISTRY: A EUROPEAN JOURNAL, pp. 2988 – 2992 . https://doi.org/10.1002/chem.201605816