Lithium Aryloxide Thin Films with Guest-Induced Structural Transformation by ALD/MLD
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Journal Title
Journal ISSN
Volume Title
A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä
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Date
2017
Major/Subject
Mcode
Degree programme
Language
en
Pages
5
2988 – 2992
2988 – 2992
Series
CHEMISTRY: A EUROPEAN JOURNAL
Abstract
Crystalline Li-organic thin films are grown with the atomic/molecular layer deposition (ALD/MLD) technique from lithium hexamethyldisilazide and hydroquinone. The as-deposited films are found to undergo a reversible structural transformation upon exposure to ambient humid air. According to density functional theory calculations, the guest-induced transformation may be related to an unsaturated Li site in the crystal structure.Description
| openaire: EC/FP7/339478/EU//LAYERENG-HYBMAT
Keywords
Atomic layer deposition, Coordination polymer, Lithium organic hybrid, Molecular layer deposition, Thin film
Citation
Nisula , M , Linnera , J , Karttunen , A J & Karppinen , M 2017 , ' Lithium Aryloxide Thin Films with Guest-Induced Structural Transformation by ALD/MLD ' , CHEMISTRY: A EUROPEAN JOURNAL , pp. 2988 – 2992 . https://doi.org/10.1002/chem.201605816