Investigating yttrium ruthenate pyrochlore as an anodic electrocatalyst in proton exchange membrane water electrolysis

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Journal ISSN

Volume Title

Insinööritieteiden korkeakoulu | Master's thesis

Date

2023-08-21

Department

Major/Subject

Energy Systems

Mcode

Degree programme

Nordic Master Programme in Innovative and Sustainable Energy Engineering (ISEE)

Language

en

Pages

85+38

Series

Abstract

As the energy transition progresses, the demand for energy storage solutions to support intermittent renewable production is ever-increasing. Hydrogen storage is receiving increased interest and support due to its promising sustainability and flexibility. Proton- exchange, or polymer electrolyte, membrane (PEM) electrolyzers are a key technology supporting hydrogen storage systems. Reducing anodic catalysts costs by proposing alternatives to the standard and expensive rare-earth metal oxide catalysts are key to accelerating commercialization of PEM water electrolyzers. Yttrium ruthenate pyrochlore Y2Ru2O7 (YRO) has stood out as promising alternative due to enhanced oxygen evolution reaction (OER) activity, high stability, and low onset overpotential in acidic PEM conditions. Obstacles remain, including low electrical conductivity. This work investigates YRO as a suitable OER catalyst for PEM water electrolysis. In assessing the catalyst suitability, the impacts of pre-calcination in sol-gel synthesis of YRO, mechanical post-processing of powders, and ink preparation on result quality and catalyst performance are unveiled via rotating disc electrode (RDE) characterization. Pre-calcination, grinding and milling, and lengthy and cooled sonication of inks contribute to improved results quality. A half-cell apparatus is developed and verified as a proof of concept for increased electrochemical characterization flexibility and improved representation of electrolyzer operational conditions. Test station membrane electrode assembly (MEA) characterization reveals undoped YRO undergoes severe and irreversible degradation as a single component catalyst in PEM electrolysis. Hydrogen crossover and low electrical conductivity are chief drivers for the high losses and degrading performance.

Description

Supervisor

Santasalo-Aarnio, Annukka

Thesis advisor

Martin, Andrew
Seland, Frode

Keywords

water electrolysis, anodic catalysts, rotating disc electrode, half-cell development, in-situ characterization

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