Design of experiments as a tool to guide the preparation of tailor-made activated carbons
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A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä
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Date
2023-03-09
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en
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13
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Scientific Reports, Volume 13, issue 1
Abstract
Activated carbon produced from biomass exhibits a high specific surface area due to the natural hierarchical porous structure of the precursor material. To reduce production costs of activated carbon, bio-waste materials receive more and more attention, which has led to a steep increase in the number of publications over the past decade. However, the characteristics of activated carbon are highly dependent on the properties of the precursor material used, making it difficult to draw assumptions about activation conditions for new precursor materials based on published work. Here, we introduce a Design of Experiment methodology with a Central Composite Design to better predict the properties of activated carbons from biomass. As a model precursor, we employ well-defined regenerated cellulose-based fibers which contain 25 wt.% chitosan as intrinsic dehydration catalyst and nitrogen donor. The use of the DoE methodology opens up the possibility to better identify the crucial dependencies between activation temperature and impregnation ratio on the yield, surface morphology, porosity and chemical composition of the activated carbon, independent of the used biomass. The use of DoE yields contour plots, which allows for more facile analysis on correlations between activation conditions and activated carbon properties, thus enabling its tailor-made manufacturing.Description
| openaire: EC/H2020/715788/EU//WoCaFi The authors want to thank Hilda Zahra for providing the cellulose-chitosan composite fibers used in this work. JS would like to thank Lukas Fliri for the EA data evaluation. The TU Graz Open Access Publishing Fund is acknowledged for financial support. Funding Information: MH acknowledges funding from the European Research Council under the European Union’s Horizon 2020 research and innovation programme (Grant Agreement No 715788). JS was partly funded by the Academy of Finland’s Flagship Programme under Projects No. 318890 and 318891 (Competence Center for Materials Bioeconomy, FinnCERES). Publisher Copyright: © 2023, The Author(s).
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Schaubeder, J B, Guizani, C, Selinger, J, Mautner, A, Hummel, M & Spirk, S 2023, ' Design of experiments as a tool to guide the preparation of tailor-made activated carbons ', Scientific Reports, vol. 13, no. 1, 3977 . https://doi.org/10.1038/s41598-023-30642-8