Reuse of LiCoO2 Electrodes Collected from Spent Li-Ion Batteries after Electrochemical Re-Lithiation of the Electrode

dc.contributorAalto-yliopistofi
dc.contributorAalto Universityen
dc.contributor.authorLahtinen, Katjaen_US
dc.contributor.authorRautama, Eeva Leenaen_US
dc.contributor.authorJiang, Huaen_US
dc.contributor.authorRäsänen, Samulien_US
dc.contributor.authorKallio, Tanjaen_US
dc.contributor.departmentDepartment of Chemistry and Materials Scienceen
dc.contributor.departmentOtaNanoen
dc.contributor.departmentDepartment of Applied Physicsen
dc.contributor.groupauthorElectrochemical Energy Conversionen
dc.contributor.groupauthorNanoMaterialsen
dc.date.accessioned2021-06-16T06:57:45Z
dc.date.available2021-06-16T06:57:45Z
dc.date.issued2021-06-08en_US
dc.descriptionFunding Information: This work made use of the Aalto University Otanano and RAMI infrastructures. The authors wish to thank Dr. Hannu Revitzer for performing the ICP‐OES and AAS measurements and Mr. Eldar Khabushev for assisting and partially performing the Raman measurements. The authors also thank Dr. Juho Välikangas and Mr. Tuomo Vähätiitto from University of Oulu for optimizing and preparing the pouch cells. Financial support from Academy of Finland, Strategic Research Council (the Profi 5 project) and Business Finland (the BatCircle project) is also greatly acknowledged. Publisher Copyright: © 2021 The Authors. ChemSusChem published by Wiley-VCH GmbH Copyright: Copyright 2021 Elsevier B.V., All rights reserved.
dc.description.abstractThe recycling of used Li-ion batteries is important as the consumption of batteries is increasing every year. However, the recycling of electrode materials is tedious and energy intensive with current methods, and part of the material is lost in the process. In this study, an alternative recycling method is presented to minimize the number of steps needed in the positive electrode recovery process. The electrochemical performance of aged and re-lithiated Mg−Ti-doped LiCoO2 and stoichiometric LiCoO2 was investigated and compared. The results showed that after re-lithiation the structure of original LiCoO2 was restored, the capacity of an aged LiCoO2 reverted close to the capacity of a fresh LiCoO2, and the material could thus be recovered. The re-lithiated Mg−Ti-doped LiCoO2 provided rate capability properties only slightly declined from the rate capability of a fresh material and showed promising cyclability in half-cells.en
dc.description.versionPeer revieweden
dc.format.extent11
dc.format.extent2434-2444
dc.format.mimetypeapplication/pdfen_US
dc.identifier.citationLahtinen, K, Rautama, E L, Jiang, H, Räsänen, S & Kallio, T 2021, ' Reuse of LiCoO 2 Electrodes Collected from Spent Li-Ion Batteries after Electrochemical Re-Lithiation of the Electrode ', ChemSusChem, vol. 14, no. 11, pp. 2434-2444 . https://doi.org/10.1002/cssc.202100629en
dc.identifier.doi10.1002/cssc.202100629en_US
dc.identifier.issn1864-5631
dc.identifier.issn1864-564X
dc.identifier.otherPURE UUID: dffe2f89-232a-4b4b-ac76-257d934bc809en_US
dc.identifier.otherPURE ITEMURL: https://research.aalto.fi/en/publications/dffe2f89-232a-4b4b-ac76-257d934bc809en_US
dc.identifier.otherPURE LINK: http://www.scopus.com/inward/record.url?scp=85105316489&partnerID=8YFLogxKen_US
dc.identifier.otherPURE FILEURL: https://research.aalto.fi/files/64984975/CHEM_Lahtinen_et_al_Reuse_of_LiCo2_Electrodes_2021_ChemSusChem.pdfen_US
dc.identifier.urihttps://aaltodoc.aalto.fi/handle/123456789/108158
dc.identifier.urnURN:NBN:fi:aalto-202106167416
dc.language.isoenen
dc.publisherWILEY-VCH VERLAG
dc.relation.ispartofseriesChemSusChemen
dc.relation.ispartofseriesVolume 14, issue 11en
dc.rightsopenAccessen
dc.subject.keywordDopingen_US
dc.subject.keywordenergy conversionen_US
dc.subject.keywordlithiationen_US
dc.subject.keywordlithium-ion batteriesen_US
dc.subject.keywordrenewable resourcesen_US
dc.titleReuse of LiCoO2 Electrodes Collected from Spent Li-Ion Batteries after Electrochemical Re-Lithiation of the Electrodeen
dc.typeA1 Alkuperäisartikkeli tieteellisessä aikakauslehdessäfi
dc.type.versionpublishedVersion
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