2-Methylresorcinarene: a very high packing coefficient in a mono-anion based dimeric capsule and the X-ray crystal structure of the tetra-anion

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dc.contributorAalto-yliopistofi
dc.contributorAalto Universityen
dc.contributor.authorPuttreddy, Rakesh
dc.contributor.authorBeyeh, Ngong Kodiah
dc.contributor.authorKalenius, Elina
dc.contributor.authorRas, Robin H A
dc.contributor.authorRissanen, Kari
dc.contributor.departmentUniversity of Jyväskylä
dc.contributor.departmentDepartment of Applied Physics
dc.date.accessioned2017-03-23T11:25:45Z
dc.date.available2017-03-23T11:25:45Z
dc.date.issued2016-05
dc.description.abstractMono- and tetra-deprotonated 2-methylresorcinarene anions (1 and 2) as their trans-1,4-diammoniumcyclohexane (TDAC)2+ inclusion complexes are reported. The mono-anion forms a fully closed dimeric capsule [1·H2O·MeOH]2 2- with a cavity volume of 165 3 and (TDAC)2+ as the guest with an extremely high packing coefficient, PC = 84.2%, while the tetra-anion forms a close-packed structure with two structurally isomeric tetra-anions 2a and 2b with a 50:50 ratio in the crystal lattice.en
dc.description.versionPeer revieweden
dc.format.extent4
dc.format.extent8115-8118
dc.format.mimetypeapplication/pdf
dc.identifier.citationPuttreddy , R , Beyeh , N K , Kalenius , E , Ras , R H A & Rissanen , K 2016 , ' 2-Methylresorcinarene: a very high packing coefficient in a mono-anion based dimeric capsule and the X-ray crystal structure of the tetra-anion ' , Chemical Communications , vol. 52 , no. 52 , pp. 8115-8118 . https://doi.org/10.1039/c6cc03289cen
dc.identifier.doi10.1039/c6cc03289c
dc.identifier.issn1359-7345
dc.identifier.issn1364-548X
dc.identifier.otherPURE UUID: 9558938c-95dd-4226-8003-fbe3698b1a1c
dc.identifier.otherPURE ITEMURL: https://research.aalto.fi/en/publications/9558938c-95dd-4226-8003-fbe3698b1a1c
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dc.identifier.otherPURE FILEURL: https://research.aalto.fi/files/11179981/2_Methylresorcinarene.pdf
dc.identifier.urihttps://aaltodoc.aalto.fi/handle/123456789/24915
dc.identifier.urnURN:NBN:fi:aalto-201703233158
dc.language.isoenen
dc.relation.ispartofseriesCHEMICAL COMMUNICATIONSen
dc.relation.ispartofseriesVolume 52, issue 52en
dc.rightsopenAccessen
dc.title2-Methylresorcinarene: a very high packing coefficient in a mono-anion based dimeric capsule and the X-ray crystal structure of the tetra-anionen
dc.typeA1 Alkuperäisartikkeli tieteellisessä aikakauslehdessäfi
dc.type.versionpublishedVersion
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