2-Methylresorcinarene: a very high packing coefficient in a mono-anion based dimeric capsule and the X-ray crystal structure of the tetra-anion

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A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä
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Author
Date
2016-05
Department
University of Jyväskylä
Department of Applied Physics
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Mcode
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Language
en
Pages
4
8115-8118
Series
CHEMICAL COMMUNICATIONS, Volume 52, issue 52
Abstract
Mono- and tetra-deprotonated 2-methylresorcinarene anions (1 and 2) as their trans-1,4-diammoniumcyclohexane (TDAC)2+ inclusion complexes are reported. The mono-anion forms a fully closed dimeric capsule [1·H2O·MeOH]2 2- with a cavity volume of 165 3 and (TDAC)2+ as the guest with an extremely high packing coefficient, PC = 84.2%, while the tetra-anion forms a close-packed structure with two structurally isomeric tetra-anions 2a and 2b with a 50:50 ratio in the crystal lattice.
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DOI
10.1039/c6cc03289c
Citation
Puttreddy , R , Beyeh , N K , Kalenius , E , Ras , R H A & Rissanen , K 2016 , ' 2-Methylresorcinarene: a very high packing coefficient in a mono-anion based dimeric capsule and the X-ray crystal structure of the tetra-anion ' , Chemical Communications , vol. 52 , no. 52 , pp. 8115-8118 . https://doi.org/10.1039/c6cc03289c
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https://urn.fi/URN:NBN:fi:aalto-201703233158
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[article-cris] Perustieteiden korkeakoulu / SCI