Divergent Mechanistic Scenarios for the C−sp2 and C−sp3 C−H Insertion of Aurated Aryl Cations

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dc.contributorAalto-yliopistofi
dc.contributorAalto Universityen
dc.contributor.authorBucher, Janinaen_US
dc.contributor.authorWurm, Thomasen_US
dc.contributor.authorFarshadfar, Kavehen_US
dc.contributor.authorSchukin, Michaelen_US
dc.contributor.authorUzunidis, Georgiosen_US
dc.contributor.authorRudolph, Matthiasen_US
dc.contributor.authorRominger, Franken_US
dc.contributor.authorAriafard, Alirezaen_US
dc.contributor.authorHashmi, A. Stephen K.en_US
dc.contributor.departmentDepartment of Chemistry and Materials Scienceen
dc.contributor.groupauthorComputational Chemistryen
dc.contributor.organizationHeidelberg University en_US
dc.contributor.organizationUniversity of Tasmaniaen_US
dc.date.accessioned2023-11-01T10:12:57Z
dc.date.available2023-11-01T10:12:57Z
dc.date.issued2023-10-13en_US
dc.descriptionFunding Information: J. Bucher is grateful for a Chemiefonds scholarship of the Fonds der Chemischen Industrie. The authors thank Umicore AG & Co. KG for the generous donation of gold salts. Publisher Copyright: © 2023 The Authors. Advanced Synthesis & Catalysis published by Wiley-VCH GmbH.
dc.description.abstractBy employing the sterically highly demanding steering ligand IPr* at a gold(I) center, it is possible to induce a 6-endo-dig cyclization pathway in 1,5-diynes bearing terminal alkyne moieties. The resulting aurated naphthyl cations are utilized for the intermolecular formation of C−C bonds via C−H insertion of aromatic and aliphatic C−H bonds. The mechanisms of these transformations were studied by quantum chemical calculations.en
dc.description.versionPeer revieweden
dc.format.extent8
dc.format.extent3320-3327
dc.format.mimetypeapplication/pdfen_US
dc.identifier.citationBucher, J, Wurm, T, Farshadfar, K, Schukin, M, Uzunidis, G, Rudolph, M, Rominger, F, Ariafard, A & Hashmi, A S K 2023, ' Divergent Mechanistic Scenarios for the C− sp 2 and C− sp 3 C−H Insertion of Aurated Aryl Cations ', Advanced Synthesis and Catalysis, vol. 365, no. 19, pp. 3320-3327 . https://doi.org/10.1002/adsc.202300548en
dc.identifier.doi10.1002/adsc.202300548en_US
dc.identifier.issn1615-4150
dc.identifier.otherPURE UUID: 0f780d2f-2226-4e22-979f-0ee7732a9d44en_US
dc.identifier.otherPURE ITEMURL: https://research.aalto.fi/en/publications/0f780d2f-2226-4e22-979f-0ee7732a9d44en_US
dc.identifier.otherPURE LINK: http://www.scopus.com/inward/record.url?scp=85168593262&partnerID=8YFLogxKen_US
dc.identifier.otherPURE FILEURL: https://research.aalto.fi/files/126147234/CHEM_Bucher_et_al_Divergent_Mechanistic_2023_Adv_Synth_Catal.pdfen_US
dc.identifier.urihttps://aaltodoc.aalto.fi/handle/123456789/124351
dc.identifier.urnURN:NBN:fi:aalto-202311016719
dc.language.isoenen
dc.publisherWiley-VCH Verlag
dc.relation.ispartofseriesAdvanced Synthesis and Catalysisen
dc.relation.ispartofseriesVolume 365, issue 19en
dc.rightsopenAccessen
dc.subject.keywordaryl cationsen_US
dc.subject.keywordC−H insertionen_US
dc.subject.keyworddiynesen_US
dc.subject.keywordgold catalysisen_US
dc.subject.keywordhigh energy intermediatesen_US
dc.titleDivergent Mechanistic Scenarios for the C−sp2 and C−sp3 C−H Insertion of Aurated Aryl Cationsen
dc.typeA1 Alkuperäisartikkeli tieteellisessä aikakauslehdessäfi
dc.type.versionpublishedVersion

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