Liquid Water and Interfacial, Cubic, and Hexagonal Ice Classification through Eclipsed and Staggered Conformation Template Matching

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A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

Date

2021-04-22

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en

Pages

9
3909-3917

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Journal of Physical Chemistry B, Volume 125, issue 15

Abstract

We propose a novel method based on template matching for the recognition of liquid water, cubic ice (ice Ic), hexagonal ice (ice Ih), clathrate hydrates, and different interfacial structures in atomistic and coarse-grained simulations of water and ice. The two template matrices represent staggered and eclipsed conformations, which are the building blocks of hexagonal and cubic ice and clathrate crystals. The algorithm is rotationally invariant and highly robust against imperfections in the ice structure, and its sensitivity for recognizing ice-like structures can be tuned for different applications. Unlike most other algorithms, it can discriminate between cubic, hexagonal, clathrate, mixed, and other interfacial ice types and is therefore well suited to study complex systems and heterogeneous ice nucleation.

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Funding Information: This work was supported by the ERC Grant 692891-DAMOCLES, the Academy of Finland Flagship funding (grant no. 337549), the University of Helsinki, Faculty of Science ATMATH project, and the National Center of Meteorology (NCM), Abu Dhabi, UAE, under the UAE Research Program for Rain Enhancement Science. Supercomputing resources were provided by CSC–IT Center for Science, Ltd., Finland. B.R. is grateful to Dr. Stephen Ingram for his advice on setting up the antifreeze protein simulations. Any opinions, findings, and conclusions or recommendations expressed in this material are those of the authors and do not necessarily reflect the views of the National Center of Meteorology, Abu Dhabi, UAE, funder of the research. Publisher Copyright: © 2021 American Chemical Society. All rights reserved. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

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Roudsari, G, Veshki, F G, Reischl, B & Pakarinen, O H 2021, ' Liquid Water and Interfacial, Cubic, and Hexagonal Ice Classification through Eclipsed and Staggered Conformation Template Matching ', Journal of Physical Chemistry B, vol. 125, no. 15, pp. 3909-3917 . https://doi.org/10.1021/acs.jpcb.1c01926