Kinetics of Cu2+ Reduction and Nanoparticle Nucleation at Micro-scale 1,2-dichlorobenzene-water Interface Studied by Cyclic Voltammetry and Square-wave Voltammetry

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dc.contributorAalto-yliopistofi
dc.contributorAalto Universityen
dc.contributor.authorNieminen, Eemien_US
dc.contributor.authorMurtomäki, Lasseen_US
dc.contributor.departmentDepartment of Chemistry and Materials Scienceen
dc.contributor.groupauthorPhysical Chemistry and Electrochemistryen
dc.date.accessioned2021-09-29T09:59:55Z
dc.date.available2021-09-29T09:59:55Z
dc.date.issued2021-09en_US
dc.descriptionFunding Information: Steel and Metal Producers′ Fund of the Technology Industries of Finland Centennial Foundation is acknowledged for funding this research. Publisher Copyright: © 2021 The Authors. Electroanalysis published by Wiley-VCH GmbH.
dc.description.abstractReduction and nanoparticle nucleation of Cu2+ by decamethylferrocene was studied with cyclic and square-wave voltammetry at a microscale liquid–liquid interface established at the tip of a micropipette. With square-wave voltammetry, two reduction steps could be distinguished as two separate current waves. Comparing the experimental results of cyclic voltammetry with finite element method simulations, particle growth could be observed as an increasing limiting current. Furthermore, kinetic parameters could be estimated with square-wave voltammetry simulations following Butler-Volmer kinetics.en
dc.description.versionPeer revieweden
dc.format.extent9
dc.format.mimetypeapplication/pdfen_US
dc.identifier.citationNieminen, E & Murtomäki, L 2021, 'Kinetics of Cu 2+ Reduction and Nanoparticle Nucleation at Micro-scale 1,2-dichlorobenzene-water Interface Studied by Cyclic Voltammetry and Square-wave Voltammetry', Electroanalysis, vol. 33, no. 9, pp. 2087-2095. https://doi.org/10.1002/elan.202100172en
dc.identifier.doi10.1002/elan.202100172en_US
dc.identifier.issn1040-0397
dc.identifier.issn1521-4109
dc.identifier.otherPURE UUID: b966bdec-ee78-4ae4-a3bb-f66d19411cb4en_US
dc.identifier.otherPURE ITEMURL: https://research.aalto.fi/en/publications/b966bdec-ee78-4ae4-a3bb-f66d19411cb4en_US
dc.identifier.otherPURE FILEURL: https://research.aalto.fi/files/67773066/CHEM_Nieminen_Murtomaki_Kinetics_of_Cu2_Reduction_2021_Electroanalysis.pdf
dc.identifier.urihttps://aaltodoc.aalto.fi/handle/123456789/110188
dc.identifier.urnURN:NBN:fi:aalto-202109299388
dc.language.isoenen
dc.publisherWiley
dc.relation.fundinginfoSteel and Metal Producers′ Fund of the Technology Industries of Finland Centennial Foundation is acknowledged for funding this research.
dc.relation.ispartofseriesElectroanalysisen
dc.relation.ispartofseriesVolume 33, issue 9, pp. 2087-2095en
dc.rightsopenAccessen
dc.subject.keywordliquid-liquid interfaceen_US
dc.subject.keywordmetal reductionen_US
dc.subject.keywordsquare-wave voltammetryen_US
dc.subject.keywordmicro pipetteen_US
dc.subject.keywordfinite element simulationsen_US
dc.titleKinetics of Cu2+ Reduction and Nanoparticle Nucleation at Micro-scale 1,2-dichlorobenzene-water Interface Studied by Cyclic Voltammetry and Square-wave Voltammetryen
dc.typeA1 Alkuperäisartikkeli tieteellisessä aikakauslehdessäfi
dc.type.versionpublishedVersion

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