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Kinetics of Cu2+ Reduction and Nanoparticle Nucleation at Micro-scale 1,2-dichlorobenzene-water Interface Studied by Cyclic Voltammetry and Square-wave Voltammetry
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A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä
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en
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9
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Electroanalysis, Volume 33, issue 9, pp. 2087-2095
Abstract
Reduction and nanoparticle nucleation of Cu2+ by decamethylferrocene was studied with cyclic and square-wave voltammetry at a microscale liquid–liquid interface established at the tip of a micropipette. With square-wave voltammetry, two reduction steps could be distinguished as two separate current waves. Comparing the experimental results of cyclic voltammetry with finite element method simulations, particle growth could be observed as an increasing limiting current. Furthermore, kinetic parameters could be estimated with square-wave voltammetry simulations following Butler-Volmer kinetics.
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Funding Information: Steel and Metal Producers′ Fund of the Technology Industries of Finland Centennial Foundation is acknowledged for funding this research. Publisher Copyright: © 2021 The Authors. Electroanalysis published by Wiley-VCH GmbH.
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Nieminen, E & Murtomäki, L 2021, 'Kinetics of Cu 2+ Reduction and Nanoparticle Nucleation at Micro-scale 1,2-dichlorobenzene-water Interface Studied by Cyclic Voltammetry and Square-wave Voltammetry', Electroanalysis, vol. 33, no. 9, pp. 2087-2095. https://doi.org/10.1002/elan.202100172