Solid oxide fuel cell with a spin-coated yttria stabilized zirconia/gadolinia doped ceria bi-layer electrolyte

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A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä

Date

2022-05-03

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en

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8

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RSC Advances, Volume 12, issue 21, pp. 13220-13227

Abstract

A thin yttria stabilized zirconia (YSZ)/gadolinia doped ceria (GDC) bi-layer membrane is fabricated through the slurry spin coating technique and used as an electrolyte of a solid oxide fuel cell with La0.6Sr0.4Co0.2Fe0.8O3−δ as the cathode. The viscosity of the YSZ slurry is controlled by adding ethanol in the terpineol solvent, which shows a negligible effect on the thickness but a remarkable influence on the porosity of the YSZ film. The thickness of the YSZ layer increases with the YSZ content in the slurry. The YSZ films are pre-sintered at various temperatures, and the one sintered at 1200 °C has a moderate interaction with the GDC slurry, forming a 10 μm-thick YSZ/GDC bilayer with a low porosity and a low ohmic resistance. The corresponding single cell shows a maximum power density of 1480 mW cm−2 at 750 °C.

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Funding Information: The financial support from National Natural Science Foundation of China under contract number 22075205 and the support of Tianjin Municipal Science and Technology Commission under contract number 19JCYBJC21700 are gratefully acknowledged. The work has been also supported by the Program of Introducing Talents to the University Disciplines under file number B06006, and the Program for Changjiang Scholars and Innovative Research Teams in Universities under file number IRT 0641. Publisher Copyright: © 2022 The Royal Society of Chemistry

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Li, J, Fan, L, Hou, N, Zhao, Y & Li, Y 2022, ' Solid oxide fuel cell with a spin-coated yttria stabilized zirconia/gadolinia doped ceria bi-layer electrolyte ', RSC Advances, vol. 12, no. 21, pp. 13220-13227 . https://doi.org/10.1039/d2ra02035a