High-pressure neutron study of the morphotropic lead-zirconate-titanate

dc.contributorAalto-yliopistofi
dc.contributorAalto Universityen
dc.contributor.authorFrantti, J.
dc.contributor.authorFujioka, Y.
dc.contributor.authorZhang, Jinsuo
dc.contributor.authorWang, S.
dc.contributor.authorVogel, Sven C.
dc.contributor.authorNieminen, Risto
dc.contributor.authorAsiri, A. M.
dc.contributor.authorZhao, Y.
dc.contributor.authorObaid, A. Y.
dc.contributor.authorMkhalid, I. A.
dc.contributor.departmentDepartment of Applied Physics
dc.contributor.departmentLos Alamos National Laboratory
dc.contributor.departmentKing Abdulaziz University
dc.date.accessioned2018-05-22T14:51:44Z
dc.date.available2018-05-22T14:51:44Z
dc.date.issued2012-07-01
dc.description.abstractThe present study was dedicated to the classical piezoelectric, lead-zirconate-titanate ceramic with composition Pb(Zr 0.54Ti 0.46)O 3 at the Zr-rich side of the morphotropic phase boundary at which two phases co-exists. The pressure-induced changes in the phase fractions were studied by high-pressure neutron powder diffraction technique up to 3 GPa and 773 K. The two co-existing phases were rhombohedral R 3 c and monoclinic C m at room temperature and R 3 c and P 4 m m above 1 GPa and 400 K. The experiments show that pressure favors the R 3 c phase over the C m and P 4 m m phases, whereas at elevated temperatures entropy favours the P 4 m m phase. At 1 GPa pressure, the transition to the cubic P m 3 m phase occurred at around 600 K. Pressure lowers the C m → P 4 m m transition temperature. The C m phase was found to continuously transform to the P 4 m m phase with increasing pressure, which is inline with the usual notion that the hydrostatic pressure favours higher symmetry structures. At the same time, thephase fraction of the R 3 c phase was increasing, implying discontinuous C m → R 3 c phase transition. This is in clear contrast to the polarization rotation model according to which the C m would link the tetragonal and rhombohedral phases by being a phase in which the polarization would, more or less continuously, rotate from the tetragonal polarization direction to the rhombohedral direction. Pressure induces large changes in phase fractions contributing to the extrinsic piezoelectricity. The changes are not entirely reversible, as was revealed by noting that after high-pressure experiments the amount of rhombohedral phase was larger than initially, suggesting that on the Zr-rich side of the phase boundary the monoclinic phase is metastable. An important contribution to the intrinsic piezoelectricity was revealed: a large displacement of the B cations (Zr and Ti) with respect to the oxygen anions is induced by pressure.en
dc.description.versionPeer revieweden
dc.format.extent1-7
dc.format.mimetypeapplication/pdf
dc.identifier.citationFrantti , J , Fujioka , Y , Zhang , J , Wang , S , Vogel , S C , Nieminen , R , Asiri , A M , Zhao , Y , Obaid , A Y & Mkhalid , I A 2012 , ' High-pressure neutron study of the morphotropic lead-zirconate-titanate : Phase transitions in a two-phase system ' , Journal of Applied Physics , vol. 112 , no. 1 , 014104 , pp. 1-7 . https://doi.org/10.1063/1.4733570en
dc.identifier.doi10.1063/1.4733570
dc.identifier.issn0021-8979
dc.identifier.issn1089-7550
dc.identifier.otherPURE UUID: eb857d38-eafc-4af6-9ee8-2f0fe96686f4
dc.identifier.otherPURE ITEMURL: https://research.aalto.fi/en/publications/eb857d38-eafc-4af6-9ee8-2f0fe96686f4
dc.identifier.otherPURE LINK: http://www.scopus.com/inward/record.url?scp=84864129876&partnerID=8YFLogxK
dc.identifier.otherPURE FILEURL: https://research.aalto.fi/files/14570332/1.4733570.pdf
dc.identifier.urihttps://aaltodoc.aalto.fi/handle/123456789/31240
dc.identifier.urnURN:NBN:fi:aalto-201805222680
dc.language.isoenen
dc.relation.ispartofseriesJournal of Applied Physicsen
dc.relation.ispartofseriesVolume 112, issue 1en
dc.rightsopenAccessen
dc.titleHigh-pressure neutron study of the morphotropic lead-zirconate-titanateen
dc.typeA1 Alkuperäisartikkeli tieteellisessä aikakauslehdessäfi
dc.type.versionpublishedVersion
Files