Asymmetric synthesis of Pachastrissamine (Jaspine B) and its diastereomers via ?3-allylpalladium intermediates
| dc.contributor | Aalto-yliopisto | fi |
| dc.contributor | Aalto University | en |
| dc.contributor.author | Passiniemi, Mikko | |
| dc.contributor.author | Koskinen, Ari M.P. | |
| dc.contributor.department | Department of Chemistry | en |
| dc.date.accessioned | 2016-09-09T06:49:38Z | |
| dc.date.issued | 2011 | |
| dc.description.abstract | A short route for the synthesis of Pachastrissamine (Jaspine B), an anhydrosphingosine derivative, and all three of its diastereomers is presented. The route consists of only 9 steps from the commercially available Garner’s aldehyde. The furan framework is formed via an h3-allylpalladium intermediate. | en |
| dc.description.version | Peer reviewed | en |
| dc.format.mimetype | application/pdf | |
| dc.identifier.citation | Passiniemi, M & Koskinen, A M P 2011, 'Asymmetric synthesis of Pachastrissamine (Jaspine B) and its diastereomers via ?3-allylpalladium intermediates', Organic and Biomolecular Chemistry, vol. 9, no. 6, pp. 1774-1783. https://doi.org/10.1039/C0OB00643B | en |
| dc.identifier.doi | 10.1039/C0OB00643B | |
| dc.identifier.issn | 1477-0520 | |
| dc.identifier.issn | 1477-0539 | |
| dc.identifier.other | PURE UUID: 342f9dd9-4cb3-4ca5-bab6-a3d0d136f0cd | |
| dc.identifier.other | PURE ITEMURL: https://research.aalto.fi/en/publications/342f9dd9-4cb3-4ca5-bab6-a3d0d136f0cd | |
| dc.identifier.other | PURE LINK: http://dx.doi.org/10.1039/C0OB00643B | |
| dc.identifier.other | PURE FILEURL: https://research.aalto.fi/files/7157822/Asymmetric_synthesis_of_Pachastrissamine_Jaspine_B_.pdf | |
| dc.identifier.uri | https://aaltodoc.aalto.fi/handle/123456789/21891 | |
| dc.identifier.urn | URN:NBN:fi:aalto-201609093780 | |
| dc.language.iso | en | en |
| dc.publisher | Royal Society of Chemistry | |
| dc.relation.ispartofseries | Organic and Biomolecular Chemistry | en |
| dc.relation.ispartofseries | Volume 9, issue 6, pp. 1774-1783 | en |
| dc.rights | openAccess | en |
| dc.title | Asymmetric synthesis of Pachastrissamine (Jaspine B) and its diastereomers via ?3-allylpalladium intermediates | en |
| dc.type | A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä | fi |
| dc.type.version | acceptedVersion |